矩形碘化铌簇 Nb4OI10 - 一种窄带隙半导体

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2024-09-18 DOI:10.1002/ejic.202400329

Jan Beitlberger, Dr. Markus Ströbele, Fabian Strauß, Prof. Dr. Marcus Scheele, Dr. Carl P. Romao, Prof. Dr. Hans-Jürgen Meyer

{"title":"矩形碘化铌簇 Nb4OI10 - 一种窄带隙半导体","authors":"Jan Beitlberger, Dr. Markus Ströbele, Fabian Strauß, Prof. Dr. Marcus Scheele, Dr. Carl P. Romao, Prof. Dr. Hans-Jürgen Meyer","doi":"10.1002/ejic.202400329","DOIUrl":null,"url":null,"abstract":"A metal-rich niobium oxyiodide was prepared by soft reduction of NbI4. The structure of the new compound Nb4OI10 was determined by single-crystal X-ray diffraction and contains a rectangular Nb4(μ4-O) cluster that is interconnected into layers by iodide ligands. The local structure of the Nb4OI10 cluster bears a close relationship to a defect Nb6I11 structure. The two-dimensional van der Waals material <math></math>\nNb4OI8I4/2] is a small band-gap semiconductor (<1 eV), as analysed by electrical conductivity measurements, photoresponse, experimental band gap determination, and band structure calculation.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202400329","citationCount":"0","resultStr":"{\"title\":\"The Rectangular Niobium Oxyiodide Cluster Nb4OI10 – A Narrow Band-Gap Semiconductor\",\"authors\":\"Jan Beitlberger, Dr. Markus Ströbele, Fabian Strauß, Prof. Dr. Marcus Scheele, Dr. Carl P. Romao, Prof. Dr. Hans-Jürgen Meyer\",\"doi\":\"10.1002/ejic.202400329\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A metal-rich niobium oxyiodide was prepared by soft reduction of NbI4. The structure of the new compound Nb4OI10 was determined by single-crystal X-ray diffraction and contains a rectangular Nb4(μ4-O) cluster that is interconnected into layers by iodide ligands. The local structure of the Nb4OI10 cluster bears a close relationship to a defect Nb6I11 structure. The two-dimensional van der Waals material <math></math>\\nNb4OI8I4/2] is a small band-gap semiconductor (<1 eV), as analysed by electrical conductivity measurements, photoresponse, experimental band gap determination, and band structure calculation.\",\"PeriodicalId\":38,\"journal\":{\"name\":\"European Journal of Inorganic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202400329\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400329\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400329","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

通过软还原 NbI4 制备了富含金属的氧碘化铌。新化合物 Nb4OI10 的结构是通过单晶 X 射线衍射测定的，其中包含一个矩形 Nb4(μ4-O) 簇，该簇通过碘配体相互连接成层。Nb4OI10 簇的局部结构与有缺陷的 Nb6I11 结构关系密切。二维范德华材料 Nb4OI8I4/2] 是一种小带隙半导体（<1 eV），通过电导率测量、光响应、实验带隙测定和带结构计算进行了分析。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

The Rectangular Niobium Oxyiodide Cluster Nb4OI10 – A Narrow Band-Gap Semiconductor

查看原文本刊更多论文

The Rectangular Niobium Oxyiodide Cluster Nb4OI10 – A Narrow Band-Gap Semiconductor

A metal-rich niobium oxyiodide was prepared by soft reduction of NbI₄. The structure of the new compound Nb₄OI₁₀ was determined by single-crystal X-ray diffraction and contains a rectangular Nb₄(μ₄-O) cluster that is interconnected into layers by iodide ligands. The local structure of the Nb₄OI₁₀ cluster bears a close relationship to a defect Nb₆I₁₁ structure. The two-dimensional van der Waals material Nb₄OI₈I_4/2] is a small band-gap semiconductor (<1 eV), as analysed by electrical conductivity measurements, photoresponse, experimental band gap determination, and band structure calculation.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.