设计高能量密度锂硫袋电池的挑战和方法

IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY
Srinidi Badhrinathan, Huidong Dai, Gaind P. Pandey
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引用次数: 0

摘要

锂硫(Li-S)电池因其高比容量和硫在环境中的富集性而被广泛应用于下一代储能设备中,引起了人们的极大兴趣。然而,液态电解质锂-S 技术面临着一些挑战,例如多硫化物穿梭、阳极腐蚀和阴极动力学迟缓。锂-S 电池的实际应用需要在大规格、高能量密度的袋式电池中进行评估。高能量密度袋式电池需要严格的操作条件,如高硫负荷和操作电流、低电解液量和有限的阳极数量,这进一步限制了电化学性能和循环寿命。本综述旨在了解大型锂-S 袋式电池的不同失效机制,并制定具有高容量、库仑效率和长循环寿命的锂-S 袋式电池的关键设计参数。然后讨论了锂-S 袋式电池的最新发展,重点是固定多硫化物的阴极和电解质设计、加速硫转化动力学和锂阳极保护。此外,还综述了适用于锂-S 袋式电池研究的先进表征技术。最后,还就剩余的挑战和前景提出了一些观点,以指导未来的研究,将锂-S 技术扩大到实际应用中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Challenges and Approaches to Designing High-Energy Density Lithium-Sulfur Pouch Cells
Lithium-sulfur (Li-S) batteries are of great interest as next-generation energy storage devices in a wide variety of applications, due to their high specific capacity and the environmental abundance of sulfur. However, liquid electrolyte Li-S technology faces several challenges such as polysulfide shuttling, anode corrosion and sluggish cathode kinetics. Practical deployment of Li-S batteries requires evaluation in large-format, high energy density pouch cells. Stringent operating conditions such as high sulfur loading and operating current, low electrolyte amount, and limited anode quantity are required for high energy density pouch cells, which further curtails the electrochemical performance and cycle life. This review aims to provide an understanding of the different failure mechanisms of large-format Li-S pouch cells and formulate key design parameters of Li-S pouch cells that have high capacity, coulombic efficiency and long cycle life. Recent developments in Li-S pouch cells are then discussed, focusing on cathode and electrolyte design for polysulfide immobilization, accelerated sulfur conversion kinetics, and Li anode protection. A review of advanced characterization techniques suitable for Li-S pouch cell studies is also provided. Finally, viewpoints are offered on the remaining challenges and prospects to guide future research in scaling up Li-S technology for real-world applications.
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来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
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