G. A. Ragoisha, A. S. Bakavets, Y. M. Aniskevich, E. A. Streltsov
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引用次数: 0
摘要
通过开发基于非稳态条件下频率响应分析的表面受限电化学反应多参数监测方法,加强了通过欠电位沉积产生的电化学原子层组装纳米材料的逐层方法。这一术语的广义更新并不局限于在不同金属的电极上沉积单层金属,还涉及非金属,如 Se 和 Te、它们的化合物(CdSe、CdTe、CdS、PbTe、PbSe、Bi2Te3 等)和超晶格,如 (Bi2)m(Bi2Te3)n。在欠电位沉积和多层组装的电化学方面获得的经验也有助于材料科学的其他领域,如超级电容器研究,通过对表面受限反应的频率响应检查,可以在无法使用经典阻抗光谱和评估充放电过程中能量耗散的条件下,区分电容性电流和非电容性电流。
Electrochemically generated atomic layers as building blocks of nanomaterials
A layer-by-layer approach in the assembly of nanomaterials from the atomic layers electrochemically generated by underpotential deposition was reinforced by the development of the method of multiparametric monitoring of surface-restricted electrochemical reactions based on frequency response analysis under nonstationary conditions. The upd in a wide meaning of this term is not restricted to deposition of a monolayer of one metal onto an electrode of different metal but involves also nonmetals, such as Se and Te, their compounds (CdSe, CdTe, CdS, PbTe, PbSe, Bi2Te3, etc.) and superlattices, such as (Bi2)m(Bi2Te3)n. The experience acquired in the electrochemistry of the underpotential deposition and multilayer assembly can be also helpful in other fields of materials science, such as supercapacitor research, where the frequency response examination of the surface-restricted reactions enables the discrimination between capacitive and noncapacitive currents under conditions preventing from the use of classical impedance spectroscopy and evaluation of energy dissipation in the charge–discharge processes.
期刊介绍:
The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry.
The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces.
The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis.
The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.