镍催化的硫代羰基化反应，以磺酰氯为硫源合成硫代酯官能化的 2H-pyrones

IF 6.5 1区化学 Q2 CHEMISTRY, PHYSICAL

Journal of Catalysis Pub Date : 2024-09-18 DOI:10.1016/j.jcat.2024.115764

Chen-Yang Hou , Hucheng Ma , Ruyi Zhao , Xinxin Qi , Xiao-Feng Wu

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引用次数: 0

摘要

以磺酰氯为硫源，通过镍催化的硫代羰基化反应，探索出了一种高效、简单的合成硫代酯官能化 2H-pyrones 的方法。通过使用 Mo(CO)6 作为 CO 源和还原剂，以中等至良好的产率获得了多种含硫代酯的 2H-pyrones 。该反应为通过 Ni/Mo(CO)6 催化体系羰基合成硫代酯官能化的 2H-pyrones 提供了很好的补充。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Nickel-catalyzed thiocarbonylation for the synthesis of thioesters-functionalized 2H-pyrones with sulfonyl chlorides as the sulfur sources

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Nickel-catalyzed thiocarbonylation for the synthesis of thioesters-functionalized 2H-pyrones with sulfonyl chlorides as the sulfur sources

An efficient and straightforward protocol for the synthesis of thioesters-functionalized 2H-pyrones has been explored through a nickel-catalyzed thiocarbonylation reaction with sulfonyl chlorides as the sulfur sources. By using Mo(CO)₆ as both CO source and reductant, a diverse set of thioesters-containing 2H-pyrones have been obtained in moderate to good yields. This reaction provides a good supplement for the carbonylative synthesis of thioesters-functionalized 2H-pyrones via a Ni/Mo(CO)₆ catalytic system.

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来源期刊

Journal of Catalysis 工程技术-工程：化工

CiteScore

12.30

自引率

5.50%

发文量

447

审稿时长

31 days

期刊介绍： The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes. The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods. The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.