{"title":"评估用于测定多离子束的 MagneTOF 检测器信号","authors":"Florian Simke, Paul Fischer, Lutz Schweikhard","doi":"10.1016/j.ijms.2024.117337","DOIUrl":null,"url":null,"abstract":"<div><p>In preparation of space-change studies a MagneTOF detector is evaluated for bunches with a wide range of ion numbers. The detector is calibrated based on the comparison between single-ion counting and ion-bunch-signal integration. This allows to determine up to several ten thousands of ions in a bunch with a FWHM of about <span><math><mrow><mn>700</mn><mspace></mspace><mi>ns</mi></mrow></math></span>, the integrated signal of which increases linearly with the ion number. Furthermore, this detector limit can be circumvented using transmission-limiting elements in front of the detector. Based on this, ion bunches are investigated up to several million ions, which are prepared with a linear Paul trap. Thus, in addition to the MagneTOF detector this trap is characterized with respect to its space-charge limits at low potential-well depth.</p></div>","PeriodicalId":338,"journal":{"name":"International Journal of Mass Spectrometry","volume":"506 ","pages":"Article 117337"},"PeriodicalIF":1.6000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1387380624001489/pdfft?md5=e5709947d69dd2306df0656bec6b1120&pid=1-s2.0-S1387380624001489-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Evaluation of MagneTOF detector signals for the determination of many-ion bunches\",\"authors\":\"Florian Simke, Paul Fischer, Lutz Schweikhard\",\"doi\":\"10.1016/j.ijms.2024.117337\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In preparation of space-change studies a MagneTOF detector is evaluated for bunches with a wide range of ion numbers. The detector is calibrated based on the comparison between single-ion counting and ion-bunch-signal integration. This allows to determine up to several ten thousands of ions in a bunch with a FWHM of about <span><math><mrow><mn>700</mn><mspace></mspace><mi>ns</mi></mrow></math></span>, the integrated signal of which increases linearly with the ion number. Furthermore, this detector limit can be circumvented using transmission-limiting elements in front of the detector. Based on this, ion bunches are investigated up to several million ions, which are prepared with a linear Paul trap. Thus, in addition to the MagneTOF detector this trap is characterized with respect to its space-charge limits at low potential-well depth.</p></div>\",\"PeriodicalId\":338,\"journal\":{\"name\":\"International Journal of Mass Spectrometry\",\"volume\":\"506 \",\"pages\":\"Article 117337\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2024-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1387380624001489/pdfft?md5=e5709947d69dd2306df0656bec6b1120&pid=1-s2.0-S1387380624001489-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mass Spectrometry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387380624001489\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387380624001489","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
Evaluation of MagneTOF detector signals for the determination of many-ion bunches
In preparation of space-change studies a MagneTOF detector is evaluated for bunches with a wide range of ion numbers. The detector is calibrated based on the comparison between single-ion counting and ion-bunch-signal integration. This allows to determine up to several ten thousands of ions in a bunch with a FWHM of about , the integrated signal of which increases linearly with the ion number. Furthermore, this detector limit can be circumvented using transmission-limiting elements in front of the detector. Based on this, ion bunches are investigated up to several million ions, which are prepared with a linear Paul trap. Thus, in addition to the MagneTOF detector this trap is characterized with respect to its space-charge limits at low potential-well depth.
期刊介绍:
The journal invites papers that advance the field of mass spectrometry by exploring fundamental aspects of ion processes using both the experimental and theoretical approaches, developing new instrumentation and experimental strategies for chemical analysis using mass spectrometry, developing new computational strategies for data interpretation and integration, reporting new applications of mass spectrometry and hyphenated techniques in biology, chemistry, geology, and physics.
Papers, in which standard mass spectrometry techniques are used for analysis will not be considered.
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