评估用于多种应用的创新型 PDMS/beeswax 复合材料的机械和光学特性

IF 3.3 2区 医学 Q2 ENGINEERING, BIOMEDICAL
Ronaldo Ariati , Andrews Souza , Maria Souza , Andrea Zille , Delfim Soares , Rui Lima , João Ribeiro
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引用次数: 0

摘要

聚二甲基硅氧烷(PDMS)是一种弹性体,因其出色的物理、化学和热性能,以及生物相容性和高柔韧性,而受到研究人员的广泛关注。另一种备受关注的材料是蜂蜡,因为它是一种天然原料,具有极佳的延展性和生物降解性,并具有特殊的疏水特性。这些材料可用于疏水涂层、食品透明薄膜和透明度可控的薄膜。然而,迄今为止,还没有关于各种机械、光学和润湿性测试以及不同比例蜂蜡的研究报告。因此,我们报告了在多功能真空室中制造的添加了蜂蜡的纯 PDMS 的这些特性的实验研究。在这项研究中,我们在拉伸试验中发现,与纯 PDMS(BW0%)相比,含有 1% 蜂蜡(BW1%)的样品的变形量增加了 37%。邵氏 A 硬度测试显示,BW8% 的样品比 BW0% 的样品硬度增加了 27%。在光学测试中,将样品置于 80 °C 的温度下,与室温相比,BW1% 样品的透光率提高了 30%,使其在可见光区域与 BW0% 样品一样透明。热重分析表明,BW8% 复合材料的热稳定性可达 200 ℃。动态机械分析测试显示,BW8% 复合材料的储存模量提高了 100%。最后,在润湿性测试中,BW8% 复合材料与水的接触角为 145°。通过这些广泛的测试,蜂蜡可以增加 PDMS 的疏水性能,这种复合材料在智能设备、食品和药品包装薄膜、可控透明度薄膜、憎水表面和防腐蚀涂层等方面具有巨大的应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanical and optical properties assessment of an innovative PDMS/beeswax composite for a wide range of applications

Polydimethylsiloxane (PDMS) is an elastomer that has received primary attention from researchers due to its excellent physical, chemical, and thermal properties, together with biocompatibility and high flexibility properties. Another material that has been receiving attention is beeswax because it is a natural raw material, extremely ductile, and biodegradable, with peculiar hydrophobic properties. These materials are applied in hydrophobic coatings, clear films for foods, and films with controllable transparency. However, there is no study with a wide range of mechanical, optical, and wettability tests, and with various proportions of beeswax reported to date. Thus, we report an experimental study of these properties of pure PDMS with the addition of beeswax and manufactured in a multifunctional vacuum chamber. In this study, we report in a tensile test a 37% increase in deformation of a sample containing 1% beeswax (BW1%) when compared to pure PDMS (BW0%). The Shore A hardness test revealed a 27% increase in the BW8% sample compared to BW0%. In the optical test, the samples were subjected to a temperature of 80 °C and the BW1% sample increased 30% in transmittance when compared to room temperature making it as transparent as BW0% in the visible region. The thermogravimetric analysis showed thermal stability of the BW8% composite up to a temperature of 200 °C. The dynamic mechanical analysis test revealed a 100% increase in the storage modulus of the BW8% composite. Finally, in the wettability test, the composite BW8% presented a contact angle with water of 145°. As a result of this wide range of tests, it is possible to increase the hydrophobic properties of PDMS with beeswax and the composite has great potential for application in smart devices, food and medicines packaging films, and films with controllable transparency, water-repellent surfaces, and anti-corrosive coatings.

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来源期刊
Journal of the Mechanical Behavior of Biomedical Materials
Journal of the Mechanical Behavior of Biomedical Materials 工程技术-材料科学:生物材料
CiteScore
7.20
自引率
7.70%
发文量
505
审稿时长
46 days
期刊介绍: The Journal of the Mechanical Behavior of Biomedical Materials is concerned with the mechanical deformation, damage and failure under applied forces, of biological material (at the tissue, cellular and molecular levels) and of biomaterials, i.e. those materials which are designed to mimic or replace biological materials. The primary focus of the journal is the synthesis of materials science, biology, and medical and dental science. Reports of fundamental scientific investigations are welcome, as are articles concerned with the practical application of materials in medical devices. Both experimental and theoretical work is of interest; theoretical papers will normally include comparison of predictions with experimental data, though we recognize that this may not always be appropriate. The journal also publishes technical notes concerned with emerging experimental or theoretical techniques, letters to the editor and, by invitation, review articles and papers describing existing techniques for the benefit of an interdisciplinary readership.
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