{"title":"含有多壁碳纳米管的超高韧性水泥基复合材料的电性能和压阻性能:测试、分析和现象建模","authors":"Chaokun Hong, Qinghua Li, Zhibin Zhuang, Hongwei Xie, Shilang Xu","doi":"10.1016/j.cemconcomp.2024.105757","DOIUrl":null,"url":null,"abstract":"<div><p>This study explores the electrical and piezoresistive properties of ultra-high toughness cementitious composites (UHTCC) enhanced with multi-walled carbon nanotubes (MWCNTs) ranging from 0 to 1 wt% of cementitious binders. The observed polarization behavior is found to be analogous to the charging process of a capacitor. The polarization process and resistivity drift over time in the piezoresistive response are explained using an existing equivalent electrical circuit model incorporating a capacitor. The average results of electrical conductivity initially decrease and subsequently increase with higher MWCNTs concentrations, a phenomenon attributed to increased porosity and reduced matrix conductivity. The percolation threshold is identified at a volume fraction of 0.00387. Notably, even in the absence of MWCNTs, UHTCC materials exhibit piezoresistive properties due to the presence of metal impurities and ionic compounds. The insufficient polarization process results in an increasing trend in fractional change in resistance (FCR). The highest FCR sensitivity to external load occurs within the percolation threshold. Additionally, three equations are proposed to calculate electrical conductivity, incorporating the effects of interfaces, porosity, and matrix conductivity reduction, which align well with the experimental findings. These insights contribute to a deeper understanding of the electrical properties of UHTCC-MWCNTs composites, enabling more precise conductivity measurements and improved sensor sensitivity.</p></div>","PeriodicalId":9865,"journal":{"name":"Cement & concrete composites","volume":"154 ","pages":"Article 105757"},"PeriodicalIF":10.8000,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrical and piezoresistive properties of ultra-high toughness cementitious composite incorporating multi-walled carbon nanotubes: Testing, analyzing, and phenomenological modeling\",\"authors\":\"Chaokun Hong, Qinghua Li, Zhibin Zhuang, Hongwei Xie, Shilang Xu\",\"doi\":\"10.1016/j.cemconcomp.2024.105757\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study explores the electrical and piezoresistive properties of ultra-high toughness cementitious composites (UHTCC) enhanced with multi-walled carbon nanotubes (MWCNTs) ranging from 0 to 1 wt% of cementitious binders. The observed polarization behavior is found to be analogous to the charging process of a capacitor. The polarization process and resistivity drift over time in the piezoresistive response are explained using an existing equivalent electrical circuit model incorporating a capacitor. The average results of electrical conductivity initially decrease and subsequently increase with higher MWCNTs concentrations, a phenomenon attributed to increased porosity and reduced matrix conductivity. The percolation threshold is identified at a volume fraction of 0.00387. Notably, even in the absence of MWCNTs, UHTCC materials exhibit piezoresistive properties due to the presence of metal impurities and ionic compounds. The insufficient polarization process results in an increasing trend in fractional change in resistance (FCR). The highest FCR sensitivity to external load occurs within the percolation threshold. Additionally, three equations are proposed to calculate electrical conductivity, incorporating the effects of interfaces, porosity, and matrix conductivity reduction, which align well with the experimental findings. These insights contribute to a deeper understanding of the electrical properties of UHTCC-MWCNTs composites, enabling more precise conductivity measurements and improved sensor sensitivity.</p></div>\",\"PeriodicalId\":9865,\"journal\":{\"name\":\"Cement & concrete composites\",\"volume\":\"154 \",\"pages\":\"Article 105757\"},\"PeriodicalIF\":10.8000,\"publicationDate\":\"2024-09-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cement & concrete composites\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0958946524003305\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CONSTRUCTION & BUILDING TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cement & concrete composites","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0958946524003305","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
Electrical and piezoresistive properties of ultra-high toughness cementitious composite incorporating multi-walled carbon nanotubes: Testing, analyzing, and phenomenological modeling
This study explores the electrical and piezoresistive properties of ultra-high toughness cementitious composites (UHTCC) enhanced with multi-walled carbon nanotubes (MWCNTs) ranging from 0 to 1 wt% of cementitious binders. The observed polarization behavior is found to be analogous to the charging process of a capacitor. The polarization process and resistivity drift over time in the piezoresistive response are explained using an existing equivalent electrical circuit model incorporating a capacitor. The average results of electrical conductivity initially decrease and subsequently increase with higher MWCNTs concentrations, a phenomenon attributed to increased porosity and reduced matrix conductivity. The percolation threshold is identified at a volume fraction of 0.00387. Notably, even in the absence of MWCNTs, UHTCC materials exhibit piezoresistive properties due to the presence of metal impurities and ionic compounds. The insufficient polarization process results in an increasing trend in fractional change in resistance (FCR). The highest FCR sensitivity to external load occurs within the percolation threshold. Additionally, three equations are proposed to calculate electrical conductivity, incorporating the effects of interfaces, porosity, and matrix conductivity reduction, which align well with the experimental findings. These insights contribute to a deeper understanding of the electrical properties of UHTCC-MWCNTs composites, enabling more precise conductivity measurements and improved sensor sensitivity.
期刊介绍:
Cement & concrete composites focuses on advancements in cement-concrete composite technology and the production, use, and performance of cement-based construction materials. It covers a wide range of materials, including fiber-reinforced composites, polymer composites, ferrocement, and those incorporating special aggregates or waste materials. Major themes include microstructure, material properties, testing, durability, mechanics, modeling, design, fabrication, and practical applications. The journal welcomes papers on structural behavior, field studies, repair and maintenance, serviceability, and sustainability. It aims to enhance understanding, provide a platform for unconventional materials, promote low-cost energy-saving materials, and bridge the gap between materials science, engineering, and construction. Special issues on emerging topics are also published to encourage collaboration between materials scientists, engineers, designers, and fabricators.