Chemometric evaluation, source apportionment, and health risk analysis of natural spring water in Murree, outer Himalayas

Introduction

Contamination of water is a critical threat to human health at a global level. Water pollutants, such as heavy metals, can have adverse effects on the well-being of humans, animals, and the natural ecosystem of a region.

Study Area

Murree is the most visited tourist destination in Pakistan. The rural population of Murree uses natural spring water for drinking, household use, and irrigation.

Methods

This study assessed the elemental concentration of water from 20 natural springs in Murree using Inductively Coupled Plasma Optical Emission Spectroscopy. Source apportionment and spatial distribution of heavy metals were assessed using statistical approaches such as Pearson's correlation coefficient, principal component analysis, and interpolation. The study assessed the quality of water for drinking and irrigation in Murree's natural spring water using the metal index, sodium absorption ratio, magnesium absorption ratio, percentage sodium, Kelly's ratio, and salinity hazard. The health risks associated with heavy metals were assessed by computing Average daily dose, Hazard quotient, Hazard Index, and Cancer Risk.

Results

The mean concentration of metals in mgL^-1 varied in the following order: Ca (51.23) > Na (22.3) > Mg (16.26) > Si (6.51) > K (1.59) > Se (1.17) > Sr (0.48) > Ba (0.209) > Al (0.060) > Li (0.015) > Zn (0.005) > Fe (0.0033) > Ni (0.0032) > Cr (0.001). Metal index was calculated for Al (0.3), Ba (0.29), Cr (0.024), Ni (0.14), Fe (0.004), Zn (0.002), Sr (0.07), Mg (0.32), and Ca (0.25), revealing low levels of metal pollution. The geology of the study area was identified as the primary source of heavy metals in the water. The estimated values of health hazards showed that ingestion is the primary exposure pathway, with children having a higher risk. The health hazards posed by the heavy metal contact from the waters of Murree are not alarming. Quality indices show that the irrigation water sourced from the natural springs is of satisfactory quality.

Conclusion

The study concluded that the spring water of Murree has low concentrations of heavy metals; their concentration is dependent upon the geology of the study area and is good for drinking and irrigation.