通过与增值阳极反应耦合实现节能制氢的最新进展

IF 19.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chem Pub Date : 2024-10-10 DOI:10.1016/j.chempr.2024.08.009

Jing Li , Haohong Duan

{"title":"通过与增值阳极反应耦合实现节能制氢的最新进展","authors":"Jing Li , Haohong Duan","doi":"10.1016/j.chempr.2024.08.009","DOIUrl":null,"url":null,"abstract":"<div><div>Replacement of the oxygen evolution reaction (OER) by energetically more favorable electrooxidation reactions opens up an innovative pathway for energy-saving hydrogen (H<sub>2</sub>) production. In particular, the electrooxidation of biomass molecules, plastic wastes, and organic compounds has attracted escalating interest in recent years, owing to its potential for simultaneous H<sub>2</sub> production at the cathode and value-added chemical and fuel generation at the anode. This review article does not aim to provide a comprehensive overview of these reactions but rather to highlight the key advancements in the strategies of reaction design, activity enhancement, and selectivity regulation based on the features and challenges in each type of reaction. Through this review of key advancements, we offer mechanistic insights that guide the design of more efficient coupling systems. Lastly, the challenges and future prospects in this field are discussed.</div></div>","PeriodicalId":268,"journal":{"name":"Chem","volume":"10 10","pages":"Pages 3008-3039"},"PeriodicalIF":19.1000,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent progress in energy-saving hydrogen production by coupling with value-added anodic reactions\",\"authors\":\"Jing Li , Haohong Duan\",\"doi\":\"10.1016/j.chempr.2024.08.009\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Replacement of the oxygen evolution reaction (OER) by energetically more favorable electrooxidation reactions opens up an innovative pathway for energy-saving hydrogen (H<sub>2</sub>) production. In particular, the electrooxidation of biomass molecules, plastic wastes, and organic compounds has attracted escalating interest in recent years, owing to its potential for simultaneous H<sub>2</sub> production at the cathode and value-added chemical and fuel generation at the anode. This review article does not aim to provide a comprehensive overview of these reactions but rather to highlight the key advancements in the strategies of reaction design, activity enhancement, and selectivity regulation based on the features and challenges in each type of reaction. Through this review of key advancements, we offer mechanistic insights that guide the design of more efficient coupling systems. Lastly, the challenges and future prospects in this field are discussed.</div></div>\",\"PeriodicalId\":268,\"journal\":{\"name\":\"Chem\",\"volume\":\"10 10\",\"pages\":\"Pages 3008-3039\"},\"PeriodicalIF\":19.1000,\"publicationDate\":\"2024-10-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2451929424004248\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451929424004248","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

以能量上更有利的电氧化反应取代氧进化反应（OER），为节能制氢（H2）开辟了一条创新之路。近年来，生物质分子、塑料废料和有机化合物的电氧化反应尤其引起了越来越多的关注，因为它具有在阴极同时生产氢气、在阳极同时生产增值化学品和燃料的潜力。这篇综述文章的目的不是全面概述这些反应，而是根据每种反应的特点和挑战，重点介绍在反应设计、活性增强和选择性调节策略方面的主要进展。通过对主要进展的回顾，我们提出了指导设计更高效偶联体系的机理见解。最后，我们还讨论了这一领域的挑战和未来前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Recent progress in energy-saving hydrogen production by coupling with value-added anodic reactions

查看原文本刊更多论文

Recent progress in energy-saving hydrogen production by coupling with value-added anodic reactions

Replacement of the oxygen evolution reaction (OER) by energetically more favorable electrooxidation reactions opens up an innovative pathway for energy-saving hydrogen (H₂) production. In particular, the electrooxidation of biomass molecules, plastic wastes, and organic compounds has attracted escalating interest in recent years, owing to its potential for simultaneous H₂ production at the cathode and value-added chemical and fuel generation at the anode. This review article does not aim to provide a comprehensive overview of these reactions but rather to highlight the key advancements in the strategies of reaction design, activity enhancement, and selectivity regulation based on the features and challenges in each type of reaction. Through this review of key advancements, we offer mechanistic insights that guide the design of more efficient coupling systems. Lastly, the challenges and future prospects in this field are discussed.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chem Environmental Science-Environmental Chemistry

CiteScore

32.40

自引率

1.30%

发文量

281

期刊介绍： Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.