{"title":"木质素衍生碳量子点的形成机制:从化学结构到荧光行为","authors":"","doi":"10.1016/j.biortech.2024.131490","DOIUrl":null,"url":null,"abstract":"<div><p>Biomass-derived carbon quantum dots (CQDs) have the advantage of being green and low-cost, but their complex structure makes the study of their formation mechanism encounter a bottleneck. Lignin-derived CQDs were prepared by a two-step process of “low-temperature liquid depolymerization” coupled with “hydrothermal reaction” in a mild organic acid system. In the first step of the low-temperature acidolysis process, the lignin polymer first undergoes deethering and depolymerization reactions. During the hydrothermal process in the second step, the organic small molecules on the surface of the supernatant are enriched with reactive groups that are dehydrated, condensed, crosslinked, and carbonized under high temperature and pressure to form CQDs. On the other hand, these activated large sp<sup>2</sup> carbon domains in the oxidized solid residue from lignin acidolysis undergo hydrothermal cleavage under high-temperature and high-pressure conditions, followed by deoxygenation and eventual decomposition into small carbon domain CQDs products. Among them, the supernatant component C1 after lignin acidolysis with abundant N-H and C-OH reactive groups is targeted as a key precursor for the formation of lignin-derived CQDs, and the resulting CQDs have both the highest QY (19.5%) and yield (16.5%). This study bridges the research gap on the formation mechanism of biomass-derived CQDs and offers a reference for the sustainable preparation of biomass-derived CQDs.</p></div>","PeriodicalId":258,"journal":{"name":"Bioresource Technology","volume":null,"pages":null},"PeriodicalIF":9.7000,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Formation mechanism of lignin-derived carbon quantum dots: From chemical structures to fluorescent behaviors\",\"authors\":\"\",\"doi\":\"10.1016/j.biortech.2024.131490\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Biomass-derived carbon quantum dots (CQDs) have the advantage of being green and low-cost, but their complex structure makes the study of their formation mechanism encounter a bottleneck. Lignin-derived CQDs were prepared by a two-step process of “low-temperature liquid depolymerization” coupled with “hydrothermal reaction” in a mild organic acid system. In the first step of the low-temperature acidolysis process, the lignin polymer first undergoes deethering and depolymerization reactions. During the hydrothermal process in the second step, the organic small molecules on the surface of the supernatant are enriched with reactive groups that are dehydrated, condensed, crosslinked, and carbonized under high temperature and pressure to form CQDs. On the other hand, these activated large sp<sup>2</sup> carbon domains in the oxidized solid residue from lignin acidolysis undergo hydrothermal cleavage under high-temperature and high-pressure conditions, followed by deoxygenation and eventual decomposition into small carbon domain CQDs products. Among them, the supernatant component C1 after lignin acidolysis with abundant N-H and C-OH reactive groups is targeted as a key precursor for the formation of lignin-derived CQDs, and the resulting CQDs have both the highest QY (19.5%) and yield (16.5%). This study bridges the research gap on the formation mechanism of biomass-derived CQDs and offers a reference for the sustainable preparation of biomass-derived CQDs.</p></div>\",\"PeriodicalId\":258,\"journal\":{\"name\":\"Bioresource Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":9.7000,\"publicationDate\":\"2024-09-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bioresource Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0960852424011945\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"AGRICULTURAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bioresource Technology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0960852424011945","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"AGRICULTURAL ENGINEERING","Score":null,"Total":0}
Formation mechanism of lignin-derived carbon quantum dots: From chemical structures to fluorescent behaviors
Biomass-derived carbon quantum dots (CQDs) have the advantage of being green and low-cost, but their complex structure makes the study of their formation mechanism encounter a bottleneck. Lignin-derived CQDs were prepared by a two-step process of “low-temperature liquid depolymerization” coupled with “hydrothermal reaction” in a mild organic acid system. In the first step of the low-temperature acidolysis process, the lignin polymer first undergoes deethering and depolymerization reactions. During the hydrothermal process in the second step, the organic small molecules on the surface of the supernatant are enriched with reactive groups that are dehydrated, condensed, crosslinked, and carbonized under high temperature and pressure to form CQDs. On the other hand, these activated large sp2 carbon domains in the oxidized solid residue from lignin acidolysis undergo hydrothermal cleavage under high-temperature and high-pressure conditions, followed by deoxygenation and eventual decomposition into small carbon domain CQDs products. Among them, the supernatant component C1 after lignin acidolysis with abundant N-H and C-OH reactive groups is targeted as a key precursor for the formation of lignin-derived CQDs, and the resulting CQDs have both the highest QY (19.5%) and yield (16.5%). This study bridges the research gap on the formation mechanism of biomass-derived CQDs and offers a reference for the sustainable preparation of biomass-derived CQDs.
期刊介绍:
Bioresource Technology publishes original articles, review articles, case studies, and short communications covering the fundamentals, applications, and management of bioresource technology. The journal seeks to advance and disseminate knowledge across various areas related to biomass, biological waste treatment, bioenergy, biotransformations, bioresource systems analysis, and associated conversion or production technologies.
Topics include:
• Biofuels: liquid and gaseous biofuels production, modeling and economics
• Bioprocesses and bioproducts: biocatalysis and fermentations
• Biomass and feedstocks utilization: bioconversion of agro-industrial residues
• Environmental protection: biological waste treatment
• Thermochemical conversion of biomass: combustion, pyrolysis, gasification, catalysis.