Rebecca Grün, Atheer Saad Hashim, Dr.-Ing. Constantino Grau Turuelo, Prof. Dr. Cornelia Breitkopf
{"title":"通过频率响应技术了解沸石 13X 上的二氧化碳扩散情况","authors":"Rebecca Grün, Atheer Saad Hashim, Dr.-Ing. Constantino Grau Turuelo, Prof. Dr. Cornelia Breitkopf","doi":"10.1002/cmtd.202400006","DOIUrl":null,"url":null,"abstract":"<p>Zeolite 13X is an excellent candidate for the capture of CO<sub>2</sub>. However, this system needs to be investigated in more detail with regard to adsorption and diffusion. For this purpose, frequency response (FR) measurements were carried out with binderless zeolite 13X (NaMSX) and CO<sub>2</sub>. The size of the particles and the sample amount were modified in order to investigate their effects on diffusion processes. Macropore diffusion was detected and the corresponding diffusion coefficients were determined. The mentioned system was additionally used to evaluate the performance of the in-house FR apparatus.</p>","PeriodicalId":72562,"journal":{"name":"Chemistry methods : new approaches to solving problems in chemistry","volume":"4 9","pages":""},"PeriodicalIF":6.1000,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cmtd.202400006","citationCount":"0","resultStr":"{\"title\":\"Insights into CO2 Diffusion on Zeolite 13X via Frequency Response Technique\",\"authors\":\"Rebecca Grün, Atheer Saad Hashim, Dr.-Ing. Constantino Grau Turuelo, Prof. Dr. Cornelia Breitkopf\",\"doi\":\"10.1002/cmtd.202400006\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Zeolite 13X is an excellent candidate for the capture of CO<sub>2</sub>. However, this system needs to be investigated in more detail with regard to adsorption and diffusion. For this purpose, frequency response (FR) measurements were carried out with binderless zeolite 13X (NaMSX) and CO<sub>2</sub>. The size of the particles and the sample amount were modified in order to investigate their effects on diffusion processes. Macropore diffusion was detected and the corresponding diffusion coefficients were determined. The mentioned system was additionally used to evaluate the performance of the in-house FR apparatus.</p>\",\"PeriodicalId\":72562,\"journal\":{\"name\":\"Chemistry methods : new approaches to solving problems in chemistry\",\"volume\":\"4 9\",\"pages\":\"\"},\"PeriodicalIF\":6.1000,\"publicationDate\":\"2024-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cmtd.202400006\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry methods : new approaches to solving problems in chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cmtd.202400006\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry methods : new approaches to solving problems in chemistry","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cmtd.202400006","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Insights into CO2 Diffusion on Zeolite 13X via Frequency Response Technique
Zeolite 13X is an excellent candidate for the capture of CO2. However, this system needs to be investigated in more detail with regard to adsorption and diffusion. For this purpose, frequency response (FR) measurements were carried out with binderless zeolite 13X (NaMSX) and CO2. The size of the particles and the sample amount were modified in order to investigate their effects on diffusion processes. Macropore diffusion was detected and the corresponding diffusion coefficients were determined. The mentioned system was additionally used to evaluate the performance of the in-house FR apparatus.