三种固体氧化物电解槽(SOEC)中的多物理场耦合和热应力研究

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY
Yachao Tu , Jin Chai , Shian Li , Fang Han , Zhonggang Zhang , Weiqiang Cai
{"title":"三种固体氧化物电解槽(SOEC)中的多物理场耦合和热应力研究","authors":"Yachao Tu ,&nbsp;Jin Chai ,&nbsp;Shian Li ,&nbsp;Fang Han ,&nbsp;Zhonggang Zhang ,&nbsp;Weiqiang Cai","doi":"10.1016/j.ijoes.2024.100789","DOIUrl":null,"url":null,"abstract":"<div><p>Solid Oxide Electrolysis Cell (SOEC) technology emerges as a promising method for hydrogen production. In this study, a 3D geometric and mathematical model for a planar cathode-supported SOEC is established. The developed model is validated in agreement with the experimental data obtained at same conditions. Three different channel types (square, trapezoidal, and rectangular) are simulated and compared in terms of cell overall performance and various transport phenomena occurred inside the SOEC. Local distribution of gas concentrations of reactants and products, temperature, current density, and thermal stress under different channel types are predicted and presented. The findings reveal that the fuel utilization efficiency of the rectangular channel is approximately 6.77 % and 22.68 % higher than that of the square and trapezoidal channels, respectively. The maximum temperature value of the counter-flow arrangement in the rectangular channel is around 20 K lower than that of the co-flow arrangement. When the cathode inlet volume flow rate is around 10 sccm, the fuel utilization efficiency of the electrolysis cell reaches its maximum, with a value 60 % higher than that at a cathode inlet volume flow rate of 50 sccm. However, the thermal stress distribution uniformity of the rectangular channel is not as good as that of the square and trapezoidal channels, and the trapezoidal channel exhibits the most uniform stress distribution at the electrolyte among the three-channel types.</p></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"19 10","pages":"Article 100789"},"PeriodicalIF":1.3000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1452398124003304/pdfft?md5=2357e86a0b17248d73a502dafa389700&pid=1-s2.0-S1452398124003304-main.pdf","citationCount":"0","resultStr":"{\"title\":\"The study of multiphysics field coupling and thermal stress in three types of Solid Oxide Electrolysis Cells (SOEC)\",\"authors\":\"Yachao Tu ,&nbsp;Jin Chai ,&nbsp;Shian Li ,&nbsp;Fang Han ,&nbsp;Zhonggang Zhang ,&nbsp;Weiqiang Cai\",\"doi\":\"10.1016/j.ijoes.2024.100789\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Solid Oxide Electrolysis Cell (SOEC) technology emerges as a promising method for hydrogen production. In this study, a 3D geometric and mathematical model for a planar cathode-supported SOEC is established. The developed model is validated in agreement with the experimental data obtained at same conditions. Three different channel types (square, trapezoidal, and rectangular) are simulated and compared in terms of cell overall performance and various transport phenomena occurred inside the SOEC. Local distribution of gas concentrations of reactants and products, temperature, current density, and thermal stress under different channel types are predicted and presented. The findings reveal that the fuel utilization efficiency of the rectangular channel is approximately 6.77 % and 22.68 % higher than that of the square and trapezoidal channels, respectively. The maximum temperature value of the counter-flow arrangement in the rectangular channel is around 20 K lower than that of the co-flow arrangement. When the cathode inlet volume flow rate is around 10 sccm, the fuel utilization efficiency of the electrolysis cell reaches its maximum, with a value 60 % higher than that at a cathode inlet volume flow rate of 50 sccm. However, the thermal stress distribution uniformity of the rectangular channel is not as good as that of the square and trapezoidal channels, and the trapezoidal channel exhibits the most uniform stress distribution at the electrolyte among the three-channel types.</p></div>\",\"PeriodicalId\":13872,\"journal\":{\"name\":\"International Journal of Electrochemical Science\",\"volume\":\"19 10\",\"pages\":\"Article 100789\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1452398124003304/pdfft?md5=2357e86a0b17248d73a502dafa389700&pid=1-s2.0-S1452398124003304-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Electrochemical Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1452398124003304\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Electrochemical Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1452398124003304","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0

摘要

固体氧化物电解池(SOEC)技术是一种前景广阔的制氢方法。本研究建立了平面阴极支撑 SOEC 的三维几何和数学模型。所建立的模型与在相同条件下获得的实验数据进行了验证。模拟了三种不同类型的通道(正方形、梯形和矩形),并就电池的整体性能和 SOEC 内部发生的各种传输现象进行了比较。预测并展示了不同通道类型下反应物和生成物的气体浓度、温度、电流密度和热应力的局部分布。研究结果表明,矩形通道的燃料利用效率比正方形和梯形通道分别高出约 6.77 % 和 22.68 %。矩形通道中逆流布置的最高温度值比同流布置低 20 K 左右。当阴极入口体积流量约为 10 sccm 时,电解槽的燃料利用效率达到最大值,比阴极入口体积流量为 50 sccm 时高 60%。不过,矩形通道的热应力分布均匀性不如方形和梯形通道,而梯形通道在三通道类型中电解质处的应力分布最为均匀。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The study of multiphysics field coupling and thermal stress in three types of Solid Oxide Electrolysis Cells (SOEC)

Solid Oxide Electrolysis Cell (SOEC) technology emerges as a promising method for hydrogen production. In this study, a 3D geometric and mathematical model for a planar cathode-supported SOEC is established. The developed model is validated in agreement with the experimental data obtained at same conditions. Three different channel types (square, trapezoidal, and rectangular) are simulated and compared in terms of cell overall performance and various transport phenomena occurred inside the SOEC. Local distribution of gas concentrations of reactants and products, temperature, current density, and thermal stress under different channel types are predicted and presented. The findings reveal that the fuel utilization efficiency of the rectangular channel is approximately 6.77 % and 22.68 % higher than that of the square and trapezoidal channels, respectively. The maximum temperature value of the counter-flow arrangement in the rectangular channel is around 20 K lower than that of the co-flow arrangement. When the cathode inlet volume flow rate is around 10 sccm, the fuel utilization efficiency of the electrolysis cell reaches its maximum, with a value 60 % higher than that at a cathode inlet volume flow rate of 50 sccm. However, the thermal stress distribution uniformity of the rectangular channel is not as good as that of the square and trapezoidal channels, and the trapezoidal channel exhibits the most uniform stress distribution at the electrolyte among the three-channel types.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信