Daohua Bao, Guoguang Cheng, Jinwen Zhang, Zhixiang Wang, Wei Li, Yao Li, Tao Zhang
{"title":"D2 高速铁路车轮钢中大尺寸 CaO-Al2O3-SiO2 杂质的特征、形成机理及去除方法","authors":"Daohua Bao, Guoguang Cheng, Jinwen Zhang, Zhixiang Wang, Wei Li, Yao Li, Tao Zhang","doi":"10.1002/srin.202400497","DOIUrl":null,"url":null,"abstract":"<p>The characteristics, formation mechanism, and removal of large-sized CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> inclusions in D2 high-speed railway wheel steel are investigated. Large-sized CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> inclusions are present in the continuous casting billet, with SiO<sub>2</sub> and CaO content ranging from 5 to 15 and 30 to 65 wt%, respectively. The size mainly exceeds 10 μm. These inclusions originate from the calcium-treatment stage of the refining process, during which liquid CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> inclusions are formed in the liquid steel. The contact angle between these inclusions and the liquid steel is below 40°, which results in excellent wettability. Consequently, the inclusions are difficult to remove from the liquid steel and are thus inherited into the billet. By reducing the SiO<sub>2</sub> content and controlling CaO content between 8 and 30 wt%, small-sized inclusions are formed. This requires reasonable control of the Al and Ca content in the liquid steel. When the Al and Ca content in liquid steel is maintained at 0.012 wt% and 8 ppm, respectively, the inclusions in the billet are mainly CaO·6Al<sub>2</sub>O<sub>3</sub> (CA<sub>6</sub>) and CaO·2Al<sub>2</sub>O<sub>3</sub> (CA<sub>2</sub>), both under 5 μm in size. These inclusions represent the suitable inclusions in steel.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"95 12","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Characteristics, Formation Mechanism, and Removal of Large-Sized CaO–Al2O3–SiO2 Inclusions in D2 High-Speed Railway Wheel Steel\",\"authors\":\"Daohua Bao, Guoguang Cheng, Jinwen Zhang, Zhixiang Wang, Wei Li, Yao Li, Tao Zhang\",\"doi\":\"10.1002/srin.202400497\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The characteristics, formation mechanism, and removal of large-sized CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> inclusions in D2 high-speed railway wheel steel are investigated. Large-sized CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> inclusions are present in the continuous casting billet, with SiO<sub>2</sub> and CaO content ranging from 5 to 15 and 30 to 65 wt%, respectively. The size mainly exceeds 10 μm. These inclusions originate from the calcium-treatment stage of the refining process, during which liquid CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> inclusions are formed in the liquid steel. The contact angle between these inclusions and the liquid steel is below 40°, which results in excellent wettability. Consequently, the inclusions are difficult to remove from the liquid steel and are thus inherited into the billet. By reducing the SiO<sub>2</sub> content and controlling CaO content between 8 and 30 wt%, small-sized inclusions are formed. This requires reasonable control of the Al and Ca content in the liquid steel. When the Al and Ca content in liquid steel is maintained at 0.012 wt% and 8 ppm, respectively, the inclusions in the billet are mainly CaO·6Al<sub>2</sub>O<sub>3</sub> (CA<sub>6</sub>) and CaO·2Al<sub>2</sub>O<sub>3</sub> (CA<sub>2</sub>), both under 5 μm in size. These inclusions represent the suitable inclusions in steel.</p>\",\"PeriodicalId\":21929,\"journal\":{\"name\":\"steel research international\",\"volume\":\"95 12\",\"pages\":\"\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-08-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"steel research international\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/srin.202400497\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"steel research international","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/srin.202400497","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Characteristics, Formation Mechanism, and Removal of Large-Sized CaO–Al2O3–SiO2 Inclusions in D2 High-Speed Railway Wheel Steel
The characteristics, formation mechanism, and removal of large-sized CaO–Al2O3–SiO2 inclusions in D2 high-speed railway wheel steel are investigated. Large-sized CaO–Al2O3–SiO2 inclusions are present in the continuous casting billet, with SiO2 and CaO content ranging from 5 to 15 and 30 to 65 wt%, respectively. The size mainly exceeds 10 μm. These inclusions originate from the calcium-treatment stage of the refining process, during which liquid CaO–Al2O3–SiO2 inclusions are formed in the liquid steel. The contact angle between these inclusions and the liquid steel is below 40°, which results in excellent wettability. Consequently, the inclusions are difficult to remove from the liquid steel and are thus inherited into the billet. By reducing the SiO2 content and controlling CaO content between 8 and 30 wt%, small-sized inclusions are formed. This requires reasonable control of the Al and Ca content in the liquid steel. When the Al and Ca content in liquid steel is maintained at 0.012 wt% and 8 ppm, respectively, the inclusions in the billet are mainly CaO·6Al2O3 (CA6) and CaO·2Al2O3 (CA2), both under 5 μm in size. These inclusions represent the suitable inclusions in steel.
期刊介绍:
steel research international is a journal providing a forum for the publication of high-quality manuscripts in areas ranging from process metallurgy and metal forming to materials engineering as well as process control and testing. The emphasis is on steel and on materials involved in steelmaking and the processing of steel, such as refractories and slags.
steel research international welcomes manuscripts describing basic scientific research as well as industrial research. The journal received a further increased, record-high Impact Factor of 1.522 (2018 Journal Impact Factor, Journal Citation Reports (Clarivate Analytics, 2019)).
The journal was formerly well known as "Archiv für das Eisenhüttenwesen" and "steel research"; with effect from January 1, 2006, the former "Scandinavian Journal of Metallurgy" merged with Steel Research International.
Hot Topics:
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