{"title":"金纳米粒子的功函数、静电力显微镜、可调光致发光以及金纳米粒子/罗丹明 6G 纳米复合材料的等离子相互作用","authors":"Ishaq Musa, Jamal Ghabboun","doi":"10.1007/s11468-024-02484-1","DOIUrl":null,"url":null,"abstract":"<p>The work function and tunable photoluminescence of gold nanoparticles (AuNPs) and their interaction with Rhodamine 6G (R6G) molecules were characterized using scanning probe microscopy (SPM) and spectroscopy techniques. Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy (KPFM) were employed to analyze the surface roughness and work function of AuNPs ranging in size from 3 to 21 nm. According to measurements with Kelvin Probe Force Microscopy (KPFM), the work functions for AuNPs are approximately 5.17 eV, 5.14 eV, and 5.13 eV for the range of sizes of nanoparticles. It was observed that larger AuNPs have increased surface roughness and consequently decreased work function. Additionally, phase imaging and Electrostatic Force Microscopy (EFM) were utilized to further investigate the AuNPs/R6G composites, revealing their surface nanoscale distribution and their electrical properties. In addition, the tunable photoluminescence of AuNPs based on excitation wavelength was studied, showing that as the excitation wavelength increases, the photoluminescence shifts to higher emission wavelengths and the peak intensity increases. Furthermore, UV–visible absorption and photoluminescence spectroscopy were employed to investigate the optical properties of AuNPs added to Rhodamine 6G molecules, revealing an enhancement in absorption and a reduction in photoluminescence.</p>","PeriodicalId":736,"journal":{"name":"Plasmonics","volume":null,"pages":null},"PeriodicalIF":3.3000,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Work Function, Electrostatic Force Microscopy, Tunable Photoluminescence of Gold Nanoparticles, and Plasmonic Interaction of Gold Nanoparticles/Rhodamine 6G Nanocomposite\",\"authors\":\"Ishaq Musa, Jamal Ghabboun\",\"doi\":\"10.1007/s11468-024-02484-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The work function and tunable photoluminescence of gold nanoparticles (AuNPs) and their interaction with Rhodamine 6G (R6G) molecules were characterized using scanning probe microscopy (SPM) and spectroscopy techniques. Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy (KPFM) were employed to analyze the surface roughness and work function of AuNPs ranging in size from 3 to 21 nm. According to measurements with Kelvin Probe Force Microscopy (KPFM), the work functions for AuNPs are approximately 5.17 eV, 5.14 eV, and 5.13 eV for the range of sizes of nanoparticles. It was observed that larger AuNPs have increased surface roughness and consequently decreased work function. Additionally, phase imaging and Electrostatic Force Microscopy (EFM) were utilized to further investigate the AuNPs/R6G composites, revealing their surface nanoscale distribution and their electrical properties. In addition, the tunable photoluminescence of AuNPs based on excitation wavelength was studied, showing that as the excitation wavelength increases, the photoluminescence shifts to higher emission wavelengths and the peak intensity increases. Furthermore, UV–visible absorption and photoluminescence spectroscopy were employed to investigate the optical properties of AuNPs added to Rhodamine 6G molecules, revealing an enhancement in absorption and a reduction in photoluminescence.</p>\",\"PeriodicalId\":736,\"journal\":{\"name\":\"Plasmonics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2024-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Plasmonics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1007/s11468-024-02484-1\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plasmonics","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1007/s11468-024-02484-1","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Work Function, Electrostatic Force Microscopy, Tunable Photoluminescence of Gold Nanoparticles, and Plasmonic Interaction of Gold Nanoparticles/Rhodamine 6G Nanocomposite
The work function and tunable photoluminescence of gold nanoparticles (AuNPs) and their interaction with Rhodamine 6G (R6G) molecules were characterized using scanning probe microscopy (SPM) and spectroscopy techniques. Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy (KPFM) were employed to analyze the surface roughness and work function of AuNPs ranging in size from 3 to 21 nm. According to measurements with Kelvin Probe Force Microscopy (KPFM), the work functions for AuNPs are approximately 5.17 eV, 5.14 eV, and 5.13 eV for the range of sizes of nanoparticles. It was observed that larger AuNPs have increased surface roughness and consequently decreased work function. Additionally, phase imaging and Electrostatic Force Microscopy (EFM) were utilized to further investigate the AuNPs/R6G composites, revealing their surface nanoscale distribution and their electrical properties. In addition, the tunable photoluminescence of AuNPs based on excitation wavelength was studied, showing that as the excitation wavelength increases, the photoluminescence shifts to higher emission wavelengths and the peak intensity increases. Furthermore, UV–visible absorption and photoluminescence spectroscopy were employed to investigate the optical properties of AuNPs added to Rhodamine 6G molecules, revealing an enhancement in absorption and a reduction in photoluminescence.
期刊介绍:
Plasmonics is an international forum for the publication of peer-reviewed leading-edge original articles that both advance and report our knowledge base and practice of the interactions of free-metal electrons, Plasmons.
Topics covered include notable advances in the theory, Physics, and applications of surface plasmons in metals, to the rapidly emerging areas of nanotechnology, biophotonics, sensing, biochemistry and medicine. Topics, including the theory, synthesis and optical properties of noble metal nanostructures, patterned surfaces or materials, continuous or grated surfaces, devices, or wires for their multifarious applications are particularly welcome. Typical applications might include but are not limited to, surface enhanced spectroscopic properties, such as Raman scattering or fluorescence, as well developments in techniques such as surface plasmon resonance and near-field scanning optical microscopy.