{"title":"嵌入还原氧化石墨烯的氧化钒纳米棒的稳健双色电致色性:揭示机理","authors":"Saheli Bhattacharjee, Sovandeb Sen, Susmita Kundu","doi":"10.1149/1945-7111/ad6e1f","DOIUrl":null,"url":null,"abstract":"Vanadium pentoxide (V<sub>2</sub>O<sub>5</sub>), associated with both cathodic and anodic coloration, is considered as one of the best electrochromic (EC) materials for energy-saving smart electronics. Here we present the fabrication and detailed mechanism analysis for improving the electrochromic properties of V<sub>2</sub>O<sub>5</sub> incorporated in a reduced graphene oxide (rGO) matrix using a facile wet chemical method. The microstructural study disclosed the formation of prominent V<sub>2</sub>O<sub>5</sub> nanorods embedded in the rGO matrix. The optimized electrochromic film resulted in coloration (t<sub>c</sub>) and bleaching time (t<sub>b</sub>) of ∼6.2 and ∼4.8 s, respectively, much faster than the color switching kinetics of the pristine V<sub>2</sub>O<sub>5</sub> sample (t<sub>c</sub> ∼ 19.4 s, t<sub>b</sub> ∼ 15.3 s). The more dispersed structure also ensured an approximate 400% enhancement in the optical modulation of EC film and reflected a noticeable improvement in the coloration efficiency (∼347 cm<sup>2</sup>/C) of V<sub>2</sub>O<sub>5</sub> film. Modification with rGO resulted in an outstanding improvement in the electrochemical redox stability of V<sub>2</sub>O<sub>5</sub> up to 5000 CV cycles with minimum deterioration in the curve area. The formation of nanorod structure was the prime factor for better ion diffusion and thereby facilitating enhanced performance.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"44 1","pages":""},"PeriodicalIF":3.1000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Robust Dual-Color Electrochromism of Vanadium Oxide Nanorods Embedded on Reduced Graphene Oxide: Unraveling the Mechanism\",\"authors\":\"Saheli Bhattacharjee, Sovandeb Sen, Susmita Kundu\",\"doi\":\"10.1149/1945-7111/ad6e1f\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Vanadium pentoxide (V<sub>2</sub>O<sub>5</sub>), associated with both cathodic and anodic coloration, is considered as one of the best electrochromic (EC) materials for energy-saving smart electronics. Here we present the fabrication and detailed mechanism analysis for improving the electrochromic properties of V<sub>2</sub>O<sub>5</sub> incorporated in a reduced graphene oxide (rGO) matrix using a facile wet chemical method. The microstructural study disclosed the formation of prominent V<sub>2</sub>O<sub>5</sub> nanorods embedded in the rGO matrix. The optimized electrochromic film resulted in coloration (t<sub>c</sub>) and bleaching time (t<sub>b</sub>) of ∼6.2 and ∼4.8 s, respectively, much faster than the color switching kinetics of the pristine V<sub>2</sub>O<sub>5</sub> sample (t<sub>c</sub> ∼ 19.4 s, t<sub>b</sub> ∼ 15.3 s). The more dispersed structure also ensured an approximate 400% enhancement in the optical modulation of EC film and reflected a noticeable improvement in the coloration efficiency (∼347 cm<sup>2</sup>/C) of V<sub>2</sub>O<sub>5</sub> film. Modification with rGO resulted in an outstanding improvement in the electrochemical redox stability of V<sub>2</sub>O<sub>5</sub> up to 5000 CV cycles with minimum deterioration in the curve area. The formation of nanorod structure was the prime factor for better ion diffusion and thereby facilitating enhanced performance.\",\"PeriodicalId\":17364,\"journal\":{\"name\":\"Journal of The Electrochemical Society\",\"volume\":\"44 1\",\"pages\":\"\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-09-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Electrochemical Society\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1149/1945-7111/ad6e1f\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Electrochemical Society","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1149/1945-7111/ad6e1f","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Robust Dual-Color Electrochromism of Vanadium Oxide Nanorods Embedded on Reduced Graphene Oxide: Unraveling the Mechanism
Vanadium pentoxide (V2O5), associated with both cathodic and anodic coloration, is considered as one of the best electrochromic (EC) materials for energy-saving smart electronics. Here we present the fabrication and detailed mechanism analysis for improving the electrochromic properties of V2O5 incorporated in a reduced graphene oxide (rGO) matrix using a facile wet chemical method. The microstructural study disclosed the formation of prominent V2O5 nanorods embedded in the rGO matrix. The optimized electrochromic film resulted in coloration (tc) and bleaching time (tb) of ∼6.2 and ∼4.8 s, respectively, much faster than the color switching kinetics of the pristine V2O5 sample (tc ∼ 19.4 s, tb ∼ 15.3 s). The more dispersed structure also ensured an approximate 400% enhancement in the optical modulation of EC film and reflected a noticeable improvement in the coloration efficiency (∼347 cm2/C) of V2O5 film. Modification with rGO resulted in an outstanding improvement in the electrochemical redox stability of V2O5 up to 5000 CV cycles with minimum deterioration in the curve area. The formation of nanorod structure was the prime factor for better ion diffusion and thereby facilitating enhanced performance.
期刊介绍:
The Journal of The Electrochemical Society (JES) is the leader in the field of solid-state and electrochemical science and technology. This peer-reviewed journal publishes an average of 450 pages of 70 articles each month. Articles are posted online, with a monthly paper edition following electronic publication. The ECS membership benefits package includes access to the electronic edition of this journal.