温度对 K 长石导电性的影响

IF 1.8 3区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS
Supti Sadhukhan, Tapati Dutta
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引用次数: 0

摘要

K 长石约占地壳的 60%,对于了解多孔岩石的导电性至关重要。它的电特性对于陶瓷、电绝缘和导电聚合物的应用至关重要。在这项工作中,我们研究了富含钾长石的岩石在不同温度、高pH值和低pH值条件下电导率的时间演化。模拟离子迁移的随机漫步者根据适当的流体力学方程、溶解和沉淀动力学进行运动。考虑到温度、流体 pH 值和岩石中 K 长石丰度等参数的变化,对导电率进行了计算。结果发现,电导率随温度的升高而升高,直到一个临界值,之后电导率下降。电导率上升和下降的剧烈程度可以通过电导率质量因子来量化。我们发现,随着 K 长石矿物含量的减少,导电率也会增加。我们对导电率的模拟结果与所报告的实验趋势非常吻合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Temperature effects on the electrical conductivity of K-feldspar

K-feldspar, which constitutes about 60 % $\%$ of the Earth's crust, is crucial for understanding electrical conductivity in porous rocks. Its electrical properties are vital for applications in ceramics, electrical insulation and conductive polymers. In this work, we study the time evolution of electrical conductivity of K-feldspar-rich rocks with varying temperatures, at high and low pH, which has been studied through simulation using time domain random walk. Random walkers, mimicking ions in transport, move in accordance with appropriate hydrodynamic equations, dissolution and precipitation kinetics. Electrical conductivity has been calculated considering variations in the parameters of temperature, fluid pH and the abundance of K-feldspar in rocks. Electrical conductivity is found to increase with temperature up to a critical value, after which it decreases. The sharpness of the rise and fall in electrical conductivity is quantified through a measure defined as the conductivity quality factor Q σ $Q_{\sigma }$ . We find that Q σ $Q_{\sigma }$ increases with a decrease in the availability of K-feldspar mineral. Our simulated results of electrical conductivity show a good match with the experimental trends reported.

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来源期刊
Geophysical Prospecting
Geophysical Prospecting 地学-地球化学与地球物理
CiteScore
4.90
自引率
11.50%
发文量
118
审稿时长
4.5 months
期刊介绍: Geophysical Prospecting publishes the best in primary research on the science of geophysics as it applies to the exploration, evaluation and extraction of earth resources. Drawing heavily on contributions from researchers in the oil and mineral exploration industries, the journal has a very practical slant. Although the journal provides a valuable forum for communication among workers in these fields, it is also ideally suited to researchers in academic geophysics.
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