Ruiqi Luo, Yudong Zhao, Linzhu Wang, Chaoyi Chen, Junqi Li
{"title":"低碱性无氟精炼渣中的 CaO/Al2O3 比对 SWRS82B 钢洁净度的影响","authors":"Ruiqi Luo, Yudong Zhao, Linzhu Wang, Chaoyi Chen, Junqi Li","doi":"10.1002/srin.202400314","DOIUrl":null,"url":null,"abstract":"<p>A fluorine-free quaternary CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub>–MgO refining slag for SWRS82B coil steel is studied by considering the requirements of the steel wire. Laboratory experiments are conducted to study the equilibrium and kinetics of steel–slag reactions. The physical and chemical properties of refining slags, including the melting temperature, viscosity, and MgO solubility, are estimated by FactSage7.2 calculation. The cleanliness of SWRS82B steel refined by slags with a basicity of 1 and C/A ratio in the range of 1.36–7.13 is studied systematically. The plasticity of inclusions is studied by phase diagram and Young modulus calculation. Deoxidizing capacity and desulfurization capacity of refining slags are discussed by kinetic calculation of steel–slag reactions based on FactSage7.2 macro-editing and the kungliga tekniska högskolan model. Slag with a composition of 42%CaO–47%SiO<sub>2</sub>–4%Al<sub>2</sub>O<sub>3</sub>–7%MgO has the best refining effect, in which impurity elements are lowest and plastic inclusions with the smallest size and least quantity are obtained. The impurity elements oxygen and sulfur in steel can be controlled for 29 and 75 ppm, respectively. The average size of inclusions is 1.54 μm. The majority of inclusions are in a liquid state at 1600 °C and Young modulus of the inclusions ranges from 99.78 to 152.87 GPa.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"95 12","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of CaO/Al2O3 Ratio in Fluorine-Free Refining Slag with Low Basicity on the Cleanliness of SWRS82B Steel\",\"authors\":\"Ruiqi Luo, Yudong Zhao, Linzhu Wang, Chaoyi Chen, Junqi Li\",\"doi\":\"10.1002/srin.202400314\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A fluorine-free quaternary CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub>–MgO refining slag for SWRS82B coil steel is studied by considering the requirements of the steel wire. Laboratory experiments are conducted to study the equilibrium and kinetics of steel–slag reactions. The physical and chemical properties of refining slags, including the melting temperature, viscosity, and MgO solubility, are estimated by FactSage7.2 calculation. The cleanliness of SWRS82B steel refined by slags with a basicity of 1 and C/A ratio in the range of 1.36–7.13 is studied systematically. The plasticity of inclusions is studied by phase diagram and Young modulus calculation. Deoxidizing capacity and desulfurization capacity of refining slags are discussed by kinetic calculation of steel–slag reactions based on FactSage7.2 macro-editing and the kungliga tekniska högskolan model. Slag with a composition of 42%CaO–47%SiO<sub>2</sub>–4%Al<sub>2</sub>O<sub>3</sub>–7%MgO has the best refining effect, in which impurity elements are lowest and plastic inclusions with the smallest size and least quantity are obtained. The impurity elements oxygen and sulfur in steel can be controlled for 29 and 75 ppm, respectively. The average size of inclusions is 1.54 μm. The majority of inclusions are in a liquid state at 1600 °C and Young modulus of the inclusions ranges from 99.78 to 152.87 GPa.</p>\",\"PeriodicalId\":21929,\"journal\":{\"name\":\"steel research international\",\"volume\":\"95 12\",\"pages\":\"\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"steel research international\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/srin.202400314\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"steel research international","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/srin.202400314","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Effect of CaO/Al2O3 Ratio in Fluorine-Free Refining Slag with Low Basicity on the Cleanliness of SWRS82B Steel
A fluorine-free quaternary CaO–Al2O3–SiO2–MgO refining slag for SWRS82B coil steel is studied by considering the requirements of the steel wire. Laboratory experiments are conducted to study the equilibrium and kinetics of steel–slag reactions. The physical and chemical properties of refining slags, including the melting temperature, viscosity, and MgO solubility, are estimated by FactSage7.2 calculation. The cleanliness of SWRS82B steel refined by slags with a basicity of 1 and C/A ratio in the range of 1.36–7.13 is studied systematically. The plasticity of inclusions is studied by phase diagram and Young modulus calculation. Deoxidizing capacity and desulfurization capacity of refining slags are discussed by kinetic calculation of steel–slag reactions based on FactSage7.2 macro-editing and the kungliga tekniska högskolan model. Slag with a composition of 42%CaO–47%SiO2–4%Al2O3–7%MgO has the best refining effect, in which impurity elements are lowest and plastic inclusions with the smallest size and least quantity are obtained. The impurity elements oxygen and sulfur in steel can be controlled for 29 and 75 ppm, respectively. The average size of inclusions is 1.54 μm. The majority of inclusions are in a liquid state at 1600 °C and Young modulus of the inclusions ranges from 99.78 to 152.87 GPa.
期刊介绍：
steel research international is a journal providing a forum for the publication of high-quality manuscripts in areas ranging from process metallurgy and metal forming to materials engineering as well as process control and testing. The emphasis is on steel and on materials involved in steelmaking and the processing of steel, such as refractories and slags.
steel research international welcomes manuscripts describing basic scientific research as well as industrial research. The journal received a further increased, record-high Impact Factor of 1.522 (2018 Journal Impact Factor, Journal Citation Reports (Clarivate Analytics, 2019)).
The journal was formerly well known as "Archiv für das Eisenhüttenwesen" and "steel research"; with effect from January 1, 2006, the former "Scandinavian Journal of Metallurgy" merged with Steel Research International.
Hot Topics:
-Steels for Automotive Applications
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-Electromagnetic Processing of Metals
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