SiO2 和 Al2O3 对建筑钢材生产过程中产生的电弧界面渣的热物理性质和发泡指数的影响

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Mykyta Levchenko, Oleksandr Kovtun, Alberto Angelini, Hans Peter Markus, Dariusz Sosin, Rie Endo, Olena Volkova
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引用次数: 0

摘要

使用旋转粘度计和最大气泡压力法研究了不同二氧化硅和氧化铝含量的建筑钢材生产过程中产生的工业电弧炉(EAF)炉渣的粘度、密度和表面张力。此外,还讨论了热物理性质对发泡指数的影响。为了预测不同温度下熔渣中固相的行为,使用 FactSage 8.1 软件进行了热力学计算。实验证明,在所研究的熔渣体系中,SiO2 和 Al2O3 起着网络形成剂的作用,导致液态主导区域的粘度值增加,熔渣密度降低。氧化铝和二氧化硅的存在改变了熔渣在液态主导区的行为,使熔渣的断裂点发生变化。此外,二氧化硅的加入降低了炉渣的表面张力,证实了二氧化硅作为表面活性剂的作用。然而,由于纯氧化铝的表面张力较高,添加 Al2O3 会增加表面张力。因此,炉渣的发泡指数可增加 ≈40%,这主要是由于炉渣的聚合作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of SiO2 and Al2O3 on the Thermophysical Properties and the Foaming Index of Electric Arc Interface Slag from the Production of Construction Steel
Viscosity, density, and surface tension of an industrial electric arc furnace (EAF) slag from production of construction steel with varying SiO2 and Al2O3 contents are investigated using a rotating viscometer and the maximum bubble pressure method. In addition, influence of thermophysical properties on foaming index is discussed. To predict the behavior of the solid phase in the slag at different temperatures, thermodynamic calculations are performed using FactSage 8.1 software. The experiments demonstratethat SiO2 and Al2O3 act as network formers in the studied slag systems, resulting in increased viscosity values in the liquid‐dominant region and decreased density of the slag. The presence of alumina and silica altered the behavior of the slag in the liquid‐dominant region, shifting the breaking point of the slags. Furthermore, the addition of silica decreases the surface tension of the slag, confirming its role as a surfactant. However, the addition of Al2O3 increases the surface tension due to the high surface tension of pure alumina. Consequently, the foaming index of the slag can increase by ≈40%, primarily due to the polymerization of the slag.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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