Junnan Ding, Xing Xie, Xinyu Ouyang, Junying Chen, Fangping Ouyang, Zongwen Liu, Jian-Tao Wang, Jun He, Yanping Liu
{"title":"PdSe2 晶体中压力驱动的层间相变和增强的层间耦合","authors":"Junnan Ding, Xing Xie, Xinyu Ouyang, Junying Chen, Fangping Ouyang, Zongwen Liu, Jian-Tao Wang, Jun He, Yanping Liu","doi":"10.1007/s12274-024-6927-4","DOIUrl":null,"url":null,"abstract":"<p>Pressure exerts a profound influence on atomic configurations and interlayer interactions, thereby modulating the electronic and structural properties of materials. While high pressure has been observed to induce a structural phase transition in bulk PdSe<sub>2</sub> crystals, leading to a transition from semiconductor to metal, the high-pressure behavior of few-layer PdSe<sub>2</sub> remains elusive. Here, employing diamond anvil cell (DAC) techniques and high-pressure Raman spectroscopy, we investigate the structural evolution of layer-dependent PdSe<sub>2</sub> under high pressure. We reveal that pressure significantly enhances interlayer coupling in PdSe<sub>2</sub>, driving structural phase transitions from an orthorhombic to a cubic phase. We demonstrate that PdSe<sub>2</sub> crystals exhibit distinct layer-dependent pressure thresholds during the phase transition, with the decrease of transition pressure as the thickness of PdSe<sub>2</sub> increases. Furthermore, our results of polarized Raman spectra confirm a reduction in material anisotropy with increasing pressure. This study offers crucial insights into the structural evolution of layer-dependent van der Waals materials under pressure, advancing our understanding of their pressure-induced behaviors.\n</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"59 1","pages":""},"PeriodicalIF":9.5000,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pressure-driven layer-dependent phase transitions and enhanced interlayer coupling in PdSe2 crystals\",\"authors\":\"Junnan Ding, Xing Xie, Xinyu Ouyang, Junying Chen, Fangping Ouyang, Zongwen Liu, Jian-Tao Wang, Jun He, Yanping Liu\",\"doi\":\"10.1007/s12274-024-6927-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Pressure exerts a profound influence on atomic configurations and interlayer interactions, thereby modulating the electronic and structural properties of materials. While high pressure has been observed to induce a structural phase transition in bulk PdSe<sub>2</sub> crystals, leading to a transition from semiconductor to metal, the high-pressure behavior of few-layer PdSe<sub>2</sub> remains elusive. Here, employing diamond anvil cell (DAC) techniques and high-pressure Raman spectroscopy, we investigate the structural evolution of layer-dependent PdSe<sub>2</sub> under high pressure. We reveal that pressure significantly enhances interlayer coupling in PdSe<sub>2</sub>, driving structural phase transitions from an orthorhombic to a cubic phase. We demonstrate that PdSe<sub>2</sub> crystals exhibit distinct layer-dependent pressure thresholds during the phase transition, with the decrease of transition pressure as the thickness of PdSe<sub>2</sub> increases. Furthermore, our results of polarized Raman spectra confirm a reduction in material anisotropy with increasing pressure. This study offers crucial insights into the structural evolution of layer-dependent van der Waals materials under pressure, advancing our understanding of their pressure-induced behaviors.\\n</p>\",\"PeriodicalId\":713,\"journal\":{\"name\":\"Nano Research\",\"volume\":\"59 1\",\"pages\":\"\"},\"PeriodicalIF\":9.5000,\"publicationDate\":\"2024-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s12274-024-6927-4\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s12274-024-6927-4","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Pressure-driven layer-dependent phase transitions and enhanced interlayer coupling in PdSe2 crystals
Pressure exerts a profound influence on atomic configurations and interlayer interactions, thereby modulating the electronic and structural properties of materials. While high pressure has been observed to induce a structural phase transition in bulk PdSe2 crystals, leading to a transition from semiconductor to metal, the high-pressure behavior of few-layer PdSe2 remains elusive. Here, employing diamond anvil cell (DAC) techniques and high-pressure Raman spectroscopy, we investigate the structural evolution of layer-dependent PdSe2 under high pressure. We reveal that pressure significantly enhances interlayer coupling in PdSe2, driving structural phase transitions from an orthorhombic to a cubic phase. We demonstrate that PdSe2 crystals exhibit distinct layer-dependent pressure thresholds during the phase transition, with the decrease of transition pressure as the thickness of PdSe2 increases. Furthermore, our results of polarized Raman spectra confirm a reduction in material anisotropy with increasing pressure. This study offers crucial insights into the structural evolution of layer-dependent van der Waals materials under pressure, advancing our understanding of their pressure-induced behaviors.
期刊介绍:
Nano Research is a peer-reviewed, international and interdisciplinary research journal that focuses on all aspects of nanoscience and nanotechnology. It solicits submissions in various topical areas, from basic aspects of nanoscale materials to practical applications. The journal publishes articles on synthesis, characterization, and manipulation of nanomaterials; nanoscale physics, electrical transport, and quantum physics; scanning probe microscopy and spectroscopy; nanofluidics; nanosensors; nanoelectronics and molecular electronics; nano-optics, nano-optoelectronics, and nano-photonics; nanomagnetics; nanobiotechnology and nanomedicine; and nanoscale modeling and simulations. Nano Research offers readers a combination of authoritative and comprehensive Reviews, original cutting-edge research in Communication and Full Paper formats. The journal also prioritizes rapid review to ensure prompt publication.