Dawei Gong, Qixuan Li, Yufei Li, Qinghua Yang, Caiyu Gao, Jiku Wang and Lina Zhao
{"title":"镍催化的偶氮烯在水中高效化学选择性还原为偶氮肼","authors":"Dawei Gong, Qixuan Li, Yufei Li, Qinghua Yang, Caiyu Gao, Jiku Wang and Lina Zhao","doi":"10.1039/D4NJ03477E","DOIUrl":null,"url":null,"abstract":"<p >A nickel-catalyzed synthesis of hydrazoarenes utilizing NH<small><sub>3</sub></small>BH<small><sub>3</sub></small> in water has been developed. This simple synthesis, facilitated by a nickel catalyst, exhibits excellent chemoselectivity, with 22 examples provided without the need for any column chromatography. This strategy introduces a novel nickel-catalyzed reduction system in water, holding promise for industrial applications.</p>","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nickel-catalyzed highly efficient chemoselective reduction of azoarenes to hydrazoarenes in water†\",\"authors\":\"Dawei Gong, Qixuan Li, Yufei Li, Qinghua Yang, Caiyu Gao, Jiku Wang and Lina Zhao\",\"doi\":\"10.1039/D4NJ03477E\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A nickel-catalyzed synthesis of hydrazoarenes utilizing NH<small><sub>3</sub></small>BH<small><sub>3</sub></small> in water has been developed. This simple synthesis, facilitated by a nickel catalyst, exhibits excellent chemoselectivity, with 22 examples provided without the need for any column chromatography. This strategy introduces a novel nickel-catalyzed reduction system in water, holding promise for industrial applications.</p>\",\"PeriodicalId\":95,\"journal\":{\"name\":\"New Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d4nj03477e\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d4nj03477e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Nickel-catalyzed highly efficient chemoselective reduction of azoarenes to hydrazoarenes in water†
A nickel-catalyzed synthesis of hydrazoarenes utilizing NH3BH3 in water has been developed. This simple synthesis, facilitated by a nickel catalyst, exhibits excellent chemoselectivity, with 22 examples provided without the need for any column chromatography. This strategy introduces a novel nickel-catalyzed reduction system in water, holding promise for industrial applications.