离子尺寸、电子速率和转移因子对二维微盘热充氧化还原偶合 (+1,0) 的影响，以及在锂离子电池中的潜在应用

IF 2.7 3区化学 Q2 CHEMISTRY, ANALYTICAL

Electroanalysis Pub Date : 2024-08-22 DOI:10.1002/elan.202400134

Farid Taherkhani

{"title":"离子尺寸、电子速率和转移因子对二维微盘热充氧化还原偶合 (+1,0) 的影响，以及在锂离子电池中的潜在应用","authors":"Farid Taherkhani","doi":"10.1002/elan.202400134","DOIUrl":null,"url":null,"abstract":"Numerical finite element simulations were conducted to study the electrochemical reaction in a mixture of hetrocharge redox couple in the presence of a supporting electrolyte as a potential application in lithium ion battery, occurring on both parallel and non‐parallel two dimensional (2‐D ) microdisk electrodes. Ion size of supporting electrolyte and electron transfer rate by engineering of electrode types have significant effect on electrical storage. This study represents the first‐time exploration of the electrochemical behavior for hetrocharge +1,0 redox couple in presence of supporting electrolyte on a non‐parallel 2D microdisk. Impedance spectra were calculated for the electrochemical reaction","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"11 1","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ion Size, Electron Rate and Transfer Coefficient Effect on Hetrocharge Redox Couple (+1,0) for 2‐D Microdisk, Potential Application for Lithium Ion Battery\",\"authors\":\"Farid Taherkhani\",\"doi\":\"10.1002/elan.202400134\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Numerical finite element simulations were conducted to study the electrochemical reaction in a mixture of hetrocharge redox couple in the presence of a supporting electrolyte as a potential application in lithium ion battery, occurring on both parallel and non‐parallel two dimensional (2‐D ) microdisk electrodes. Ion size of supporting electrolyte and electron transfer rate by engineering of electrode types have significant effect on electrical storage. This study represents the first‐time exploration of the electrochemical behavior for hetrocharge +1,0 redox couple in presence of supporting electrolyte on a non‐parallel 2D microdisk. Impedance spectra were calculated for the electrochemical reaction\",\"PeriodicalId\":162,\"journal\":{\"name\":\"Electroanalysis\",\"volume\":\"11 1\",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-08-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Electroanalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/elan.202400134\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electroanalysis","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/elan.202400134","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}

引用次数: 0

摘要

我们进行了数值有限元模拟，以研究在平行和非平行二维（2-D）微盘电极上发生的、作为锂离子电池潜在应用的支撑电解质存在下的热电解氧化还原偶的混合电化学反应。支撑电解质的离子大小和电极类型工程学的电子转移率对储电量有重大影响。本研究首次探索了在非平行二维微盘上存在支撑电解质的情况下，hetrocharge +1,0 氧化还原偶的电化学行为。计算了电化学反应的阻抗谱

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Ion Size, Electron Rate and Transfer Coefficient Effect on Hetrocharge Redox Couple (+1,0) for 2‐D Microdisk, Potential Application for Lithium Ion Battery

Numerical finite element simulations were conducted to study the electrochemical reaction in a mixture of hetrocharge redox couple in the presence of a supporting electrolyte as a potential application in lithium ion battery, occurring on both parallel and non‐parallel two dimensional (2‐D ) microdisk electrodes. Ion size of supporting electrolyte and electron transfer rate by engineering of electrode types have significant effect on electrical storage. This study represents the first‐time exploration of the electrochemical behavior for hetrocharge +1,0 redox couple in presence of supporting electrolyte on a non‐parallel 2D microdisk. Impedance spectra were calculated for the electrochemical reaction

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Electroanalysis 化学-电化学

CiteScore

6.00

自引率

3.30%

发文量

222

审稿时长

2.4 months

期刊介绍： Electroanalysis is an international, peer-reviewed journal covering all branches of electroanalytical chemistry, including both fundamental and application papers as well as reviews dealing with new electrochemical sensors and biosensors, nanobioelectronics devices, analytical voltammetry, potentiometry, new electrochemical detection schemes based on novel nanomaterials, fuel cells and biofuel cells, and important practical applications. Serving as a vital communication link between the research labs and the field, Electroanalysis helps you to quickly adapt the latest innovations into practical clinical, environmental, food analysis, industrial and energy-related applications. Electroanalysis provides the most comprehensive coverage of the field and is the number one source for information on electroanalytical chemistry, electrochemical sensors and biosensors and fuel/biofuel cells.