{"title":"填充矿渣的低密度聚乙烯的热行为、阻燃性和流变特性","authors":"Xin Yan, Yuying Zhou, Shangbin Mao, Yujian Chen, Chen Liu, Hao Wu, Hu Wang, He-xin Zhang, Jian-ming Yang, Keun-Byoung Yoon","doi":"10.1007/s13726-024-01371-0","DOIUrl":null,"url":null,"abstract":"<p>In recent years, the massive discharge and irrational accumulation of slag have led to the waste of land resources and serious environmental pollution problems. In this work, to explore the potential applications of slag, it was modified with silane coupling agent 3-aminopropyltriethoxysilane (KH-550) to improve its compatibility with polymer matrix. A series of low density polyethylene (LDPE)/modified slag (MS) composites were prepared using melt blending method. The results showed that the introduction of MS significantly improved the thermal and mechanical properties of LDPE in comparison to those of its pure form. The tensile strength, tensile modulus, and <i>T</i><sub><i>d5%</i></sub> of the LDPE/MS composites with 40 wt% MS content were enhanced by 58%, 113%, and 19.9 ℃, respectively. Furthermore, dynamic rheological analysis revealed that a higher MS filler content resulted in a higher restriction on the movement of the LDPE molecular chains. The application of slag in LDPE provides a feasible method of recycling slag and promoting sustainable development.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\n","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"104 1","pages":""},"PeriodicalIF":2.4000,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermal behavior, flame retardant and rheological properties of low density polyethylene filled with slag\",\"authors\":\"Xin Yan, Yuying Zhou, Shangbin Mao, Yujian Chen, Chen Liu, Hao Wu, Hu Wang, He-xin Zhang, Jian-ming Yang, Keun-Byoung Yoon\",\"doi\":\"10.1007/s13726-024-01371-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In recent years, the massive discharge and irrational accumulation of slag have led to the waste of land resources and serious environmental pollution problems. In this work, to explore the potential applications of slag, it was modified with silane coupling agent 3-aminopropyltriethoxysilane (KH-550) to improve its compatibility with polymer matrix. A series of low density polyethylene (LDPE)/modified slag (MS) composites were prepared using melt blending method. The results showed that the introduction of MS significantly improved the thermal and mechanical properties of LDPE in comparison to those of its pure form. The tensile strength, tensile modulus, and <i>T</i><sub><i>d5%</i></sub> of the LDPE/MS composites with 40 wt% MS content were enhanced by 58%, 113%, and 19.9 ℃, respectively. Furthermore, dynamic rheological analysis revealed that a higher MS filler content resulted in a higher restriction on the movement of the LDPE molecular chains. The application of slag in LDPE provides a feasible method of recycling slag and promoting sustainable development.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical abstract</h3>\\n\",\"PeriodicalId\":601,\"journal\":{\"name\":\"Iranian Polymer Journal\",\"volume\":\"104 1\",\"pages\":\"\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2024-08-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Iranian Polymer Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s13726-024-01371-0\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Iranian Polymer Journal","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s13726-024-01371-0","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Thermal behavior, flame retardant and rheological properties of low density polyethylene filled with slag
In recent years, the massive discharge and irrational accumulation of slag have led to the waste of land resources and serious environmental pollution problems. In this work, to explore the potential applications of slag, it was modified with silane coupling agent 3-aminopropyltriethoxysilane (KH-550) to improve its compatibility with polymer matrix. A series of low density polyethylene (LDPE)/modified slag (MS) composites were prepared using melt blending method. The results showed that the introduction of MS significantly improved the thermal and mechanical properties of LDPE in comparison to those of its pure form. The tensile strength, tensile modulus, and Td5% of the LDPE/MS composites with 40 wt% MS content were enhanced by 58%, 113%, and 19.9 ℃, respectively. Furthermore, dynamic rheological analysis revealed that a higher MS filler content resulted in a higher restriction on the movement of the LDPE molecular chains. The application of slag in LDPE provides a feasible method of recycling slag and promoting sustainable development.
期刊介绍：
Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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