Samuel O Olusanya, Alex E Didunyemi, Sunday M Ajayi, Michael O Atunde, Sunday F Abimbade, Dele P Fapojuwo, Emmanuel G Olumayede, Olayide S Lawal
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引用次数: 0
摘要
本研究利用皮克林乳液系统研究了甜瓜和辣木豆荚废料中不同润湿性的苯甲酰化纤维素的界面行为。苯甲酰化纤维素是以苯甲酰氯为改性剂在水性碱性介质中制备的,并通过 X 射线衍射、热重分析、傅立叶变换红外光谱和扫描电子显微镜(SEM)进行了表征。X 射线衍射显示,辣木纤维素和甜瓜纤维素的结晶度分别为 67.47% 和 70.20%。官能化衍生物的热稳定性优于原生衍生物。扫描电子显微镜显示,由于反应物之间的反复碰撞,分离出来的纤维素在功能化后出现了表面降解。纤维素的润湿性可以通过使用不同数量的改性剂来控制,乳液的稳定性取决于乳化剂的润湿性。用从辣木豆荚废料中提取的苯甲酰化纤维素稳定的乳液具有更高的稳定性,这表明纤维素的润湿性取决于来源。
Interfacial behaviour of benzoylated cellulose of different wettability from melon and moringa pod waste
This study presents the interfacial behaviour of benzoylated cellulose of different wettability from melon and moringa pods waste using Pickering emulsions systems. The benzoylated cellulose was prepared in an aqueous alkaline medium using benzoyl chloride as a modifying agent and characterized by X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy and scanning electron microscopy (SEM). The X-ray diffraction showed that crystallinity of cellulose from moringa and melon are 67.47 and 70.20%, respectively. The functionalized derivatives are thermally stable than the native counterpart. The SEM revealed that isolated cellulose suffered surface degradation upon functionalization as a result of the repeated collision between reactants. The wetting properties of the cellulose can be controlled by using different quantities of modifying agents, and the emulsions stability depend on the wettability of the emulsifiers. The higher stability recorded for the emulsions stabilized by benzoylated cellulose from moringa pod waste revealed that cellulose wettability depends on the sources.
期刊介绍:
The Bulletin of Materials Science is a bi-monthly journal being published by the Indian Academy of Sciences in collaboration with the Materials Research Society of India and the Indian National Science Academy. The journal publishes original research articles, review articles and rapid communications in all areas of materials science. The journal also publishes from time to time important Conference Symposia/ Proceedings which are of interest to materials scientists. It has an International Advisory Editorial Board and an Editorial Committee. The Bulletin accords high importance to the quality of articles published and to keep at a minimum the processing time of papers submitted for publication.