Haiyang Tian, Yunfeng Shi, Heng Zhang, Jie Liu, Lei Li, Peng Tang
{"title":"非离子聚合物 P（AM/APEG400/NVP/SM）的合成和耐盐性能","authors":"Haiyang Tian, Yunfeng Shi, Heng Zhang, Jie Liu, Lei Li, Peng Tang","doi":"10.1007/s10965-024-04129-7","DOIUrl":null,"url":null,"abstract":"<div><p>The non-ionic hydrophobic associative copolymer AANS was synthesized by micellar polymerization using acrylamide (AM), allyl polyoxyethylene ether (APEG400), N-vinyl pyrrolidone (NVP) and stearyl methacrylate (SM) as raw materials, 2, 2'-azobis (2-methylpropionamidine) dihydrochloride (V50) as initiator, sodium dodecyl sulfate (SDS) as surfactant. The temperature resistance, salt resistance and rheological properties of the polymer were tested by viscometer and rheometer. The change of polymer microstructure in salt solution was analyzed by scanning electron microscopy. The viscosity test results showed that when the polymer concentration was higher than CAC, the polymer solution exhibited good salt resistance and presented good salt thickening performance. The effect of temperature on the salt resistance of polymer solution showed different rules. With the increase in temperature, the resistance of the polymer to NaCl decreased gradually, while the resistance of the polymer to CaCl<sub>2</sub> increased first and then decreased. The resistance of the polymer to CaCl<sub>2</sub> showed a special temperature response. Viscoelastic and shear tests showed that the polymer possessed more robust resistance to extreme sodium chloride concentration than extreme calcium chloride concentration. Micro-morphology and size analysis suggested that the microstructure of the polymer gradually became dense and compact in the salt solution. The results showed that this novel non-ionic hydrophobically associating polymer possessed potential application value in ultra-high salinity reservoirs.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"31 9","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and salt resistance of non-ionic polymer P (AM/ APEG400/NVP/SM)\",\"authors\":\"Haiyang Tian, Yunfeng Shi, Heng Zhang, Jie Liu, Lei Li, Peng Tang\",\"doi\":\"10.1007/s10965-024-04129-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The non-ionic hydrophobic associative copolymer AANS was synthesized by micellar polymerization using acrylamide (AM), allyl polyoxyethylene ether (APEG400), N-vinyl pyrrolidone (NVP) and stearyl methacrylate (SM) as raw materials, 2, 2'-azobis (2-methylpropionamidine) dihydrochloride (V50) as initiator, sodium dodecyl sulfate (SDS) as surfactant. The temperature resistance, salt resistance and rheological properties of the polymer were tested by viscometer and rheometer. The change of polymer microstructure in salt solution was analyzed by scanning electron microscopy. The viscosity test results showed that when the polymer concentration was higher than CAC, the polymer solution exhibited good salt resistance and presented good salt thickening performance. The effect of temperature on the salt resistance of polymer solution showed different rules. With the increase in temperature, the resistance of the polymer to NaCl decreased gradually, while the resistance of the polymer to CaCl<sub>2</sub> increased first and then decreased. The resistance of the polymer to CaCl<sub>2</sub> showed a special temperature response. Viscoelastic and shear tests showed that the polymer possessed more robust resistance to extreme sodium chloride concentration than extreme calcium chloride concentration. Micro-morphology and size analysis suggested that the microstructure of the polymer gradually became dense and compact in the salt solution. The results showed that this novel non-ionic hydrophobically associating polymer possessed potential application value in ultra-high salinity reservoirs.</p></div>\",\"PeriodicalId\":658,\"journal\":{\"name\":\"Journal of Polymer Research\",\"volume\":\"31 9\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10965-024-04129-7\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10965-024-04129-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Synthesis and salt resistance of non-ionic polymer P (AM/ APEG400/NVP/SM)
The non-ionic hydrophobic associative copolymer AANS was synthesized by micellar polymerization using acrylamide (AM), allyl polyoxyethylene ether (APEG400), N-vinyl pyrrolidone (NVP) and stearyl methacrylate (SM) as raw materials, 2, 2'-azobis (2-methylpropionamidine) dihydrochloride (V50) as initiator, sodium dodecyl sulfate (SDS) as surfactant. The temperature resistance, salt resistance and rheological properties of the polymer were tested by viscometer and rheometer. The change of polymer microstructure in salt solution was analyzed by scanning electron microscopy. The viscosity test results showed that when the polymer concentration was higher than CAC, the polymer solution exhibited good salt resistance and presented good salt thickening performance. The effect of temperature on the salt resistance of polymer solution showed different rules. With the increase in temperature, the resistance of the polymer to NaCl decreased gradually, while the resistance of the polymer to CaCl2 increased first and then decreased. The resistance of the polymer to CaCl2 showed a special temperature response. Viscoelastic and shear tests showed that the polymer possessed more robust resistance to extreme sodium chloride concentration than extreme calcium chloride concentration. Micro-morphology and size analysis suggested that the microstructure of the polymer gradually became dense and compact in the salt solution. The results showed that this novel non-ionic hydrophobically associating polymer possessed potential application value in ultra-high salinity reservoirs.
期刊介绍：
Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology.
As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including:
polymer synthesis;
polymer reactions;
polymerization kinetics;
polymer physics;
morphology;
structure-property relationships;
polymer analysis and characterization;
physical and mechanical properties;
electrical and optical properties;
polymer processing and rheology;
application of polymers;
supramolecular science of polymers;
polymer composites.
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