Liting Sun, Mingdong Li, Bing Nie, Jianying Ma, Chunlei Cao
{"title":"通过高温溶液聚合法制备环氧官能化丙烯腈/（乙烯/丙烯/二烯异聚合物）/苯乙烯（AES）共聚物（GAES）树脂","authors":"Liting Sun, Mingdong Li, Bing Nie, Jianying Ma, Chunlei Cao","doi":"10.1007/s10965-024-04101-5","DOIUrl":null,"url":null,"abstract":"<div><p>In this paper, epoxy-functionalized AES resins (GAES resins) were prepared by high-temperature solution polymerization, and FTIR spectrograms demonstrated the successful grafting of styrene (St), acrylonitrile (AN), and glycidyl methacrylate (GMA) onto ethylene/propylene/diene mischpolymer (EPDM) rubbers. The influences of reaction conditions, i.e. the content of initiator and chain transfer agent, EPDM and GMA on the grafting ratio, composition of free copolymers, molecular weights and polymer dispersity index (PDI) of GAES resins were detaily investigated. The influence of GMA content on the thermal stabilities of GAES resins was also discussed. Experimental results showed that under the optimized experimental conditions, the highest grafting ratio of GAES resins reached to 39.2% and the grafting efficiency was 35.3%. Under the same reaction conditions, the molecular weights of free copolymers reached to 70,000 g mol<sup>−1</sup>. The initiator had no obvious influence on the composition of free copolymers, but the component of GMA in free copolymers increased gradually with increasing content of EPDM. Thermogravimetry (TG) analysis results indicated that the incorporation of GMA decreased the thermal stabilities of GAES resins.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"31 9","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of epoxy-functionalized acrylonitrile/(ethylene/propylene/diene mischpolymer)/ styrene (AES) copolymer (GAES) resins by high-temperature solution polymerization\",\"authors\":\"Liting Sun, Mingdong Li, Bing Nie, Jianying Ma, Chunlei Cao\",\"doi\":\"10.1007/s10965-024-04101-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this paper, epoxy-functionalized AES resins (GAES resins) were prepared by high-temperature solution polymerization, and FTIR spectrograms demonstrated the successful grafting of styrene (St), acrylonitrile (AN), and glycidyl methacrylate (GMA) onto ethylene/propylene/diene mischpolymer (EPDM) rubbers. The influences of reaction conditions, i.e. the content of initiator and chain transfer agent, EPDM and GMA on the grafting ratio, composition of free copolymers, molecular weights and polymer dispersity index (PDI) of GAES resins were detaily investigated. The influence of GMA content on the thermal stabilities of GAES resins was also discussed. Experimental results showed that under the optimized experimental conditions, the highest grafting ratio of GAES resins reached to 39.2% and the grafting efficiency was 35.3%. Under the same reaction conditions, the molecular weights of free copolymers reached to 70,000 g mol<sup>−1</sup>. The initiator had no obvious influence on the composition of free copolymers, but the component of GMA in free copolymers increased gradually with increasing content of EPDM. Thermogravimetry (TG) analysis results indicated that the incorporation of GMA decreased the thermal stabilities of GAES resins.</p></div>\",\"PeriodicalId\":658,\"journal\":{\"name\":\"Journal of Polymer Research\",\"volume\":\"31 9\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10965-024-04101-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10965-024-04101-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Preparation of epoxy-functionalized acrylonitrile/(ethylene/propylene/diene mischpolymer)/ styrene (AES) copolymer (GAES) resins by high-temperature solution polymerization
In this paper, epoxy-functionalized AES resins (GAES resins) were prepared by high-temperature solution polymerization, and FTIR spectrograms demonstrated the successful grafting of styrene (St), acrylonitrile (AN), and glycidyl methacrylate (GMA) onto ethylene/propylene/diene mischpolymer (EPDM) rubbers. The influences of reaction conditions, i.e. the content of initiator and chain transfer agent, EPDM and GMA on the grafting ratio, composition of free copolymers, molecular weights and polymer dispersity index (PDI) of GAES resins were detaily investigated. The influence of GMA content on the thermal stabilities of GAES resins was also discussed. Experimental results showed that under the optimized experimental conditions, the highest grafting ratio of GAES resins reached to 39.2% and the grafting efficiency was 35.3%. Under the same reaction conditions, the molecular weights of free copolymers reached to 70,000 g mol−1. The initiator had no obvious influence on the composition of free copolymers, but the component of GMA in free copolymers increased gradually with increasing content of EPDM. Thermogravimetry (TG) analysis results indicated that the incorporation of GMA decreased the thermal stabilities of GAES resins.
期刊介绍：
Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology.
As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including:
polymer synthesis;
polymer reactions;
polymerization kinetics;
polymer physics;
morphology;
structure-property relationships;
polymer analysis and characterization;
physical and mechanical properties;
electrical and optical properties;
polymer processing and rheology;
application of polymers;
supramolecular science of polymers;
polymer composites.
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