L. O. Kozlova, I. L. Voroshilov, Yu. V. Ioni, A. G. Son, A. S. Popova, I. V. Kozerozhets
{"title":"低温合成高度分散的铝酸钙","authors":"L. O. Kozlova, I. L. Voroshilov, Yu. V. Ioni, A. G. Son, A. S. Popova, I. V. Kozerozhets","doi":"10.1134/s0036023624601077","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>A new approach to prepare highly dispersed calcium aluminate at temperatures from 900°C with desired properties (bulk density starting from 0.015 g/cm<sup>3</sup>, particle size falling in the range of 7–42 nm) is described, which consists of step-by-step heat treatment of a concentrated aqueous solution of Al(NO<sub>3</sub>)<sub>3</sub>, Ca(NO<sub>3</sub>)<sub>2</sub>, and C<sub>6</sub>H<sub>8</sub>O<sub>7</sub> in the molar ratio CaO : Al<sub>2</sub>O<sub>3</sub> = 1 : 2. The main stages of the synthesis are studied by X-ray powder diffraction, IR spectroscopy, as well as scanning and transmission electron microscopies. The highly dispersed calcium aluminate obtained using the developed approach has pronounced luminescent properties.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Low-Temperature Synthesis of Highly Dispersed Calcium Aluminate\",\"authors\":\"L. O. Kozlova, I. L. Voroshilov, Yu. V. Ioni, A. G. Son, A. S. Popova, I. V. Kozerozhets\",\"doi\":\"10.1134/s0036023624601077\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>A new approach to prepare highly dispersed calcium aluminate at temperatures from 900°C with desired properties (bulk density starting from 0.015 g/cm<sup>3</sup>, particle size falling in the range of 7–42 nm) is described, which consists of step-by-step heat treatment of a concentrated aqueous solution of Al(NO<sub>3</sub>)<sub>3</sub>, Ca(NO<sub>3</sub>)<sub>2</sub>, and C<sub>6</sub>H<sub>8</sub>O<sub>7</sub> in the molar ratio CaO : Al<sub>2</sub>O<sub>3</sub> = 1 : 2. The main stages of the synthesis are studied by X-ray powder diffraction, IR spectroscopy, as well as scanning and transmission electron microscopies. The highly dispersed calcium aluminate obtained using the developed approach has pronounced luminescent properties.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-08-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1134/s0036023624601077\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0036023624601077","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Low-Temperature Synthesis of Highly Dispersed Calcium Aluminate
Abstract
A new approach to prepare highly dispersed calcium aluminate at temperatures from 900°C with desired properties (bulk density starting from 0.015 g/cm3, particle size falling in the range of 7–42 nm) is described, which consists of step-by-step heat treatment of a concentrated aqueous solution of Al(NO3)3, Ca(NO3)2, and C6H8O7 in the molar ratio CaO : Al2O3 = 1 : 2. The main stages of the synthesis are studied by X-ray powder diffraction, IR spectroscopy, as well as scanning and transmission electron microscopies. The highly dispersed calcium aluminate obtained using the developed approach has pronounced luminescent properties.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.