二核和八核 1,2-二甲基吡啶鎓和 3-溴-1-乙基吡啶鎓碘锑酸盐(III)：晶体结构和理化性质

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Inorganic Chemistry Pub Date : 2024-08-23 DOI:10.1134/s0036023624601156

I. A. Shentseva, K. A. Tagiltsev, A. N. Usol’tsev, N. A. Korobeynikov, V. R. Shayapov, M. N. Sokolov, S. A. Adonin

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引用次数: 0

摘要

摘要通过 SbI3 与相应阳离子的碘化物在有机溶剂中的反应，制备了新的锑配合物 (3-Br-1-EtPy)3[Sb2I9] (1) 和 (1,2-Me2Py)4[Sb8I28] (2)。化合物晶体结构的特征已通过 X 射线衍射测定。这些复合物的热稳定性至少可达 200°C，带隙约为 2.2 eV。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Di- and Octanuclear 1,2-Dimethylpyridinium and 3-Bromo-1-Ethylpyridinium Iodoantimonates(III): Crystal Structure and Physicochemical Properties

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Di- and Octanuclear 1,2-Dimethylpyridinium and 3-Bromo-1-Ethylpyridinium Iodoantimonates(III): Crystal Structure and Physicochemical Properties

Abstract

New antimony complexes, (3-Br-1-EtPy)₃[Sb₂I₉] (1) and (1,2-Me₂Py)₄[Sb₈I₂₈] (2) have been prepared by the reaction of SbI₃ with iodides of the corresponding cations in organic solvents. The features of the crystal structure of the compounds have been determined by X-ray diffraction. The complexes are thermally stable at least up to 200°C and have a band gap of ~2.2 eV.

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来源期刊

Russian Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

3.10

自引率

38.10%

发文量

237

审稿时长

3 months

期刊介绍： Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.