{"title":"用于吸附废水中铅（II）的煤矸石基二氧化硅气凝胶及其机理分析","authors":"Xu Liu, Xiaomin Kong, Hao Wen, Yue Wang, Meili Wu, Hongwei Yin, Wei Qin, Manli Wang, Jun Pei, Miaoming Qu","doi":"10.1007/s11270-024-07473-y","DOIUrl":null,"url":null,"abstract":"<div><p>Coal gangue, a byproduct of coal mining with massive generation, presents a major challenge for resource utilization. In this study, SiO<sub>2</sub> aerogel was successfully fabricated from coal gangue, via a facile and cost-effective approach. The aerogel boasts an intricate network framework structure internally and functions as a mesoporous material with measurements of 154.5662 m<sup>2</sup>·g<sup>−1</sup> for specific surface area and 7.9557 nm for average pore size. Additionally, exploring the adsorption capabilities of SiO<sub>2</sub> aerogel concerning Pb(II) in wastewater, the research revealed insights. The results demonstrated that the maximum Pb(II) removal efficiency reached 94.09% under pH 6, aerogel dosage of 1.5 g·L⁻<sup>1</sup>, and initial Pb(II) concentration of 80 mg·L⁻<sup>1</sup>. The adsorption process followed the Langmuir isotherm model and pseudo-second-order kinetic model, suggesting a favorable and predominantly monomolecular layer chemisorption, and the intraparticle diffusion model suggests internal diffusion behavior during adsorption. The SiO<sub>2</sub> aerogel exhibited specific adsorption behavior towards Pb(II). This study offers a promising avenue for repurposing coal gangue while addressing the issue of Pb(II)-contaminated wastewater.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gangue-Based SiO2 Aerogel Used for Pb(II) Adsorption in Wastewater and Mechanism Analysis\",\"authors\":\"Xu Liu, Xiaomin Kong, Hao Wen, Yue Wang, Meili Wu, Hongwei Yin, Wei Qin, Manli Wang, Jun Pei, Miaoming Qu\",\"doi\":\"10.1007/s11270-024-07473-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Coal gangue, a byproduct of coal mining with massive generation, presents a major challenge for resource utilization. In this study, SiO<sub>2</sub> aerogel was successfully fabricated from coal gangue, via a facile and cost-effective approach. The aerogel boasts an intricate network framework structure internally and functions as a mesoporous material with measurements of 154.5662 m<sup>2</sup>·g<sup>−1</sup> for specific surface area and 7.9557 nm for average pore size. Additionally, exploring the adsorption capabilities of SiO<sub>2</sub> aerogel concerning Pb(II) in wastewater, the research revealed insights. The results demonstrated that the maximum Pb(II) removal efficiency reached 94.09% under pH 6, aerogel dosage of 1.5 g·L⁻<sup>1</sup>, and initial Pb(II) concentration of 80 mg·L⁻<sup>1</sup>. The adsorption process followed the Langmuir isotherm model and pseudo-second-order kinetic model, suggesting a favorable and predominantly monomolecular layer chemisorption, and the intraparticle diffusion model suggests internal diffusion behavior during adsorption. The SiO<sub>2</sub> aerogel exhibited specific adsorption behavior towards Pb(II). This study offers a promising avenue for repurposing coal gangue while addressing the issue of Pb(II)-contaminated wastewater.</p></div>\",\"PeriodicalId\":808,\"journal\":{\"name\":\"Water, Air, & Soil Pollution\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water, Air, & Soil Pollution\",\"FirstCategoryId\":\"6\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11270-024-07473-y\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water, Air, & Soil Pollution","FirstCategoryId":"6","ListUrlMain":"https://link.springer.com/article/10.1007/s11270-024-07473-y","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Gangue-Based SiO2 Aerogel Used for Pb(II) Adsorption in Wastewater and Mechanism Analysis
Coal gangue, a byproduct of coal mining with massive generation, presents a major challenge for resource utilization. In this study, SiO2 aerogel was successfully fabricated from coal gangue, via a facile and cost-effective approach. The aerogel boasts an intricate network framework structure internally and functions as a mesoporous material with measurements of 154.5662 m2·g−1 for specific surface area and 7.9557 nm for average pore size. Additionally, exploring the adsorption capabilities of SiO2 aerogel concerning Pb(II) in wastewater, the research revealed insights. The results demonstrated that the maximum Pb(II) removal efficiency reached 94.09% under pH 6, aerogel dosage of 1.5 g·L⁻1, and initial Pb(II) concentration of 80 mg·L⁻1. The adsorption process followed the Langmuir isotherm model and pseudo-second-order kinetic model, suggesting a favorable and predominantly monomolecular layer chemisorption, and the intraparticle diffusion model suggests internal diffusion behavior during adsorption. The SiO2 aerogel exhibited specific adsorption behavior towards Pb(II). This study offers a promising avenue for repurposing coal gangue while addressing the issue of Pb(II)-contaminated wastewater.
期刊介绍：
Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments.
Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation.
Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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