生物质气化的预处理研究进展

IF 9.2 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Green Chemistry Pub Date : 2024-09-16 DOI:10.1039/d4gc03243h
Quanhui Zhou , Yafei Shen , Xuehong Gu
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引用次数: 0

摘要

在随后的热转化过程中,热解是提高生物质原料质量的一种有效方法。在提高体积密度和能量密度、降低含水量和含氧量、改善疏水性等有利于运输和贮存的生物质升级方面,已广泛开展了托热效应。此外,焙烧生物质可以很容易地研磨成均匀的颗粒大小,有利于气化等下游热化学转化过程。本文报告了生物质来源的干法和湿法托烧研究进展。此外,还重点介绍了生物质干馏气化的主要发现和挑战。一般来说,生物质原料的特性可以通过高温分解工艺得到改善。用于生物质气化的热解可以提高合成气的质量。特别是,在气化过程之前,对生物质进行高温气化需要先去除挥发性物质(焦油前体)。干馏生物质的特性受干馏条件的影响很大,主要包括气氛、温度和压力。适量含氧气体的存在会使生物质的热解效果更佳。含氧气体和工业烟气余热可用于降低运行成本,从而使生物质预处理更具商业可行性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Progress in torrefaction pretreatment for biomass gasification

Progress in torrefaction pretreatment for biomass gasification

Progress in torrefaction pretreatment for biomass gasification
Torrefaction is an effective method to improve the quality of biomass feedstocks for a subsequent thermal conversion process. Torrefaction has been widely developed for biomass upgrading in terms of increasing bulk and energy densities, reducing water and oxygen contents, and improving hydrophobic properties, which are favorable for transportation and storage. Moreover, the torrefied biomass can be easily ground to even particle sizes, which favor the downstream thermochemical conversion process such as gasification. This paper reports on the progress in the dry and wet torrefaction of biomass sources. Key findings and challenges of torrefied biomass gasification are highlighted as well. In general, the properties of biomass feedstocks can be improved by the torrefaction process. Torrefaction for biomass gasification can improve the quality of syngas. In particular, gasification of torrefied biomass involves a merit of volatile matter (tar precursor) removal prior to the gasification process. The properties of torrefied biomass are significantly affected by the torrefaction conditions mainly including atmosphere, temperature, and pressure. The presence of an appropriate amount of oxygen gas leads to a superior performance for biomass torrefaction. The oxygen-containing gas and the waste heat from industrial flue gas can be utilized to reduce the operating cost, thus making the biomass torrefaction pretreatment more commercially feasible.
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来源期刊
Green Chemistry
Green Chemistry 化学-化学综合
CiteScore
16.10
自引率
7.10%
发文量
677
审稿时长
1.4 months
期刊介绍: Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.
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