用于直接甲醇燃料电池的共用阳极流场,可提高性能并减少体积

IF 3.6 4区 工程技术 Q3 ENERGY & FUELS
Yang Liu, Haibo Gan, Bin Qin, Hai Sun, Gongquan Sun
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引用次数: 0

摘要

低体积功率密度仍然是直接甲醇燃料电池(DMFC)便携式应用的一大障碍。本文在有源 DMFC 中引入了共享阳极流场(SAFF)结构,以减少堆栈体积并提高放电性能。通过极化曲线、电化学阻抗谱和电压与时间曲线,研究了采用 SAFF 结构的双电池与采用传统阳极流场(TAFF)结构的双电池在放电性能上的差异,以及工作条件对性能的影响。结果表明,与 TAFF 结构相比,SAFF 结构增强了阳极传质,从而提高了双电池的峰值功率密度和电压稳定性。此外,采用 SAFF 结构的双电池在甲醇浓度较低时也能达到最高的峰值功率密度,从而缓解了高浓度甲醇造成的甲醇交叉现象。对于 DMFC 便携式应用而言,SAFF 结构是一种极具吸引力的选择。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A Shared Anode Flow Field for Direct Methanol Fuel Cell with Enhanced Performance and Decreased Volume

A Shared Anode Flow Field for Direct Methanol Fuel Cell with Enhanced Performance and Decreased Volume

Low-volume power density remains a significant barrier to the portable application of direct methanol fuel cell (DMFC). Herein, a shared anode flow field (SAFF) structure is introduced in an active DMFC to reduce stack volume and improve discharge performance. The differences in discharge performance between the bi-cell with SAFF and the bi-cell with traditional anode flow field (TAFF), coupled with the effect of operating conditions on performance, are investigated by polarization curve, electrochemical impedance spectra, and voltage versus time curves. The results show that the SAFF structure enhances anode mass transfer, resulting in an improvement in peak power density and voltage stability of the bi-cell compared to the TAFF structure. In addition, the bi-cell with SAFF achieves its highest peak power density at a lower methanol concentration, alleviating the methanol crossover caused by high concentration. The SAFF structure is an attractive choice for DMFC portable applications.

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来源期刊
Energy technology
Energy technology ENERGY & FUELS-
CiteScore
7.00
自引率
5.30%
发文量
0
审稿时长
1.3 months
期刊介绍: Energy Technology provides a forum for researchers and engineers from all relevant disciplines concerned with the generation, conversion, storage, and distribution of energy. This new journal shall publish articles covering all technical aspects of energy process engineering from different perspectives, e.g., new concepts of energy generation and conversion; design, operation, control, and optimization of processes for energy generation (e.g., carbon capture) and conversion of energy carriers; improvement of existing processes; combination of single components to systems for energy generation; design of systems for energy storage; production processes of fuels, e.g., hydrogen, electricity, petroleum, biobased fuels; concepts and design of devices for energy distribution.
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