T. Prabhuraj, Abimannan Gomathi, Arumugam Priyadharsan, Murni Handayani, Sabah Ansar, K. A. Ramesh Kumar, Palanisamy Maadeswaran
{"title":"设计高性能 WO3/g-C3N4 Z-Scheme 光催化剂以实现有效的苯酚降解和抗菌活性","authors":"T. Prabhuraj, Abimannan Gomathi, Arumugam Priyadharsan, Murni Handayani, Sabah Ansar, K. A. Ramesh Kumar, Palanisamy Maadeswaran","doi":"10.1007/s10876-024-02692-z","DOIUrl":null,"url":null,"abstract":"<div><p>An innovative Z-scheme WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was efficiently produced via a straightforward hydrothermal method and applied to the photodegradation of phenol. The physiochemical behaviours of WO<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub>, WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was analyzed by various analytical instruments. Compared to WO<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub> single counterparts WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> Composite exhibits superior charge carriers’ separation efficiency and also Z scheme mechanism promoted the superior pollutant degradation. Subsequently, the WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite achieving 93% with rate constant 0.0184 min<sup>− 1</sup> phenol removal within 100 min. The noteworthy increased photocatalytic bustle of WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was attributed to the synergetic effect between the boundary of WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub>. Curiously, WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite validates exceptional photostability during reusable experiment, accentuating its potential as a functioning photocatalyst for phenol removal. The antimicrobial tests showed that the developed photocatalyst effectively sterilizes both gram-positive <i>Staphylococcus aureus</i> and gram-negative <i>Escherichia coli</i>. Thus, the WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> nanocomposites are robust materials suitable for use as antimicrobial agents and photocatalysts activated by sunlight.</p></div>","PeriodicalId":618,"journal":{"name":"Journal of Cluster Science","volume":"35 8","pages":"2753 - 2768"},"PeriodicalIF":2.7000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Design of a High-Performance WO3/g-C3N4 Z-Scheme Photocatalyst for Effective Phenol Degradation and Antibacterial Activity\",\"authors\":\"T. Prabhuraj, Abimannan Gomathi, Arumugam Priyadharsan, Murni Handayani, Sabah Ansar, K. A. Ramesh Kumar, Palanisamy Maadeswaran\",\"doi\":\"10.1007/s10876-024-02692-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An innovative Z-scheme WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was efficiently produced via a straightforward hydrothermal method and applied to the photodegradation of phenol. The physiochemical behaviours of WO<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub>, WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was analyzed by various analytical instruments. Compared to WO<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub> single counterparts WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> Composite exhibits superior charge carriers’ separation efficiency and also Z scheme mechanism promoted the superior pollutant degradation. Subsequently, the WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite achieving 93% with rate constant 0.0184 min<sup>− 1</sup> phenol removal within 100 min. The noteworthy increased photocatalytic bustle of WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was attributed to the synergetic effect between the boundary of WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub>. Curiously, WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite validates exceptional photostability during reusable experiment, accentuating its potential as a functioning photocatalyst for phenol removal. The antimicrobial tests showed that the developed photocatalyst effectively sterilizes both gram-positive <i>Staphylococcus aureus</i> and gram-negative <i>Escherichia coli</i>. 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Design of a High-Performance WO3/g-C3N4 Z-Scheme Photocatalyst for Effective Phenol Degradation and Antibacterial Activity
An innovative Z-scheme WO3/g-C3N4 composite was efficiently produced via a straightforward hydrothermal method and applied to the photodegradation of phenol. The physiochemical behaviours of WO3, g-C3N4, WO3/g-C3N4 composite was analyzed by various analytical instruments. Compared to WO3, g-C3N4 single counterparts WO3/g-C3N4 Composite exhibits superior charge carriers’ separation efficiency and also Z scheme mechanism promoted the superior pollutant degradation. Subsequently, the WO3/g-C3N4 composite achieving 93% with rate constant 0.0184 min− 1 phenol removal within 100 min. The noteworthy increased photocatalytic bustle of WO3/g-C3N4 composite was attributed to the synergetic effect between the boundary of WO3/g-C3N4. Curiously, WO3/g-C3N4 composite validates exceptional photostability during reusable experiment, accentuating its potential as a functioning photocatalyst for phenol removal. The antimicrobial tests showed that the developed photocatalyst effectively sterilizes both gram-positive Staphylococcus aureus and gram-negative Escherichia coli. Thus, the WO3/g-C3N4 nanocomposites are robust materials suitable for use as antimicrobial agents and photocatalysts activated by sunlight.
期刊介绍:
The journal publishes the following types of papers: (a) original and important research;
(b) authoritative comprehensive reviews or short overviews of topics of current
interest; (c) brief but urgent communications on new significant research; and (d)
commentaries intended to foster the exchange of innovative or provocative ideas, and
to encourage dialogue, amongst researchers working in different cluster
disciplines.