Yunxin Huang, Shouyan Zhao, Keyu Chen, Baocheng Huang, Rencun Jin
{"title":"基于过硫酸盐的高级氧化系统通过非辐射机制净化有机废水综述","authors":"Yunxin Huang, Shouyan Zhao, Keyu Chen, Baocheng Huang, Rencun Jin","doi":"10.1007/s11783-024-1894-2","DOIUrl":null,"url":null,"abstract":"<p>The large amount of refractory organic wastewater produced from industry and agriculture sectors poses a significant threat to both water ecosystems and human health, necessitating the exploration of cost-efficient and efficacious removal techniques. Persulfate, when activated by various catalysts, can produce oxidative species, demonstrating promising potential in remediating organic wastewater. In recent years, numerous studies have unveiled that persulfate can be readily decomposed into nonradicals, which exhibits high selectivity toward pollutants and robust performance in complex wastewater environments. However, the challenges in identifying non-radicals and the unclear catalytic mechanism hinder its further application. This paper critically reviews the research progress on non-radical oxidation in persulfate-based heterogeneous catalytic system. The main advancements and existing challenges in three non-radical oxidation pathways, i.e., singlet oxygen, electron transfer, and high-valent metal oxides, are summarized, and the key factors influencing the production of nonradicals are elaborated. The engineering aspects of non-radical oxidation system are further discussed, and the future prospects of this technology in wastewater treatment are envisaged. This review aims to bridge the knowledge gaps between current research and future requirements.\n</p>","PeriodicalId":12720,"journal":{"name":"Frontiers of Environmental Science & Engineering","volume":null,"pages":null},"PeriodicalIF":6.1000,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A review of persulfate-based advanced oxidation system for decontaminating organic wastewater via non-radical regime\",\"authors\":\"Yunxin Huang, Shouyan Zhao, Keyu Chen, Baocheng Huang, Rencun Jin\",\"doi\":\"10.1007/s11783-024-1894-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The large amount of refractory organic wastewater produced from industry and agriculture sectors poses a significant threat to both water ecosystems and human health, necessitating the exploration of cost-efficient and efficacious removal techniques. Persulfate, when activated by various catalysts, can produce oxidative species, demonstrating promising potential in remediating organic wastewater. In recent years, numerous studies have unveiled that persulfate can be readily decomposed into nonradicals, which exhibits high selectivity toward pollutants and robust performance in complex wastewater environments. However, the challenges in identifying non-radicals and the unclear catalytic mechanism hinder its further application. This paper critically reviews the research progress on non-radical oxidation in persulfate-based heterogeneous catalytic system. The main advancements and existing challenges in three non-radical oxidation pathways, i.e., singlet oxygen, electron transfer, and high-valent metal oxides, are summarized, and the key factors influencing the production of nonradicals are elaborated. The engineering aspects of non-radical oxidation system are further discussed, and the future prospects of this technology in wastewater treatment are envisaged. This review aims to bridge the knowledge gaps between current research and future requirements.\\n</p>\",\"PeriodicalId\":12720,\"journal\":{\"name\":\"Frontiers of Environmental Science & Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.1000,\"publicationDate\":\"2024-08-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Environmental Science & Engineering\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1007/s11783-024-1894-2\",\"RegionNum\":2,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Environmental Science & Engineering","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1007/s11783-024-1894-2","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
A review of persulfate-based advanced oxidation system for decontaminating organic wastewater via non-radical regime
The large amount of refractory organic wastewater produced from industry and agriculture sectors poses a significant threat to both water ecosystems and human health, necessitating the exploration of cost-efficient and efficacious removal techniques. Persulfate, when activated by various catalysts, can produce oxidative species, demonstrating promising potential in remediating organic wastewater. In recent years, numerous studies have unveiled that persulfate can be readily decomposed into nonradicals, which exhibits high selectivity toward pollutants and robust performance in complex wastewater environments. However, the challenges in identifying non-radicals and the unclear catalytic mechanism hinder its further application. This paper critically reviews the research progress on non-radical oxidation in persulfate-based heterogeneous catalytic system. The main advancements and existing challenges in three non-radical oxidation pathways, i.e., singlet oxygen, electron transfer, and high-valent metal oxides, are summarized, and the key factors influencing the production of nonradicals are elaborated. The engineering aspects of non-radical oxidation system are further discussed, and the future prospects of this technology in wastewater treatment are envisaged. This review aims to bridge the knowledge gaps between current research and future requirements.
期刊介绍:
Frontiers of Environmental Science & Engineering (FESE) is an international journal for researchers interested in a wide range of environmental disciplines. The journal''s aim is to advance and disseminate knowledge in all main branches of environmental science & engineering. The journal emphasizes papers in developing fields, as well as papers showing the interaction between environmental disciplines and other disciplines.
FESE is a bi-monthly journal. Its peer-reviewed contents consist of a broad blend of reviews, research papers, policy analyses, short communications, and opinions. Nonscheduled “special issue” and "hot topic", including a review article followed by a couple of related research articles, are organized to publish novel contributions and breaking results on all aspects of environmental field.