基于过硫酸盐的高级氧化系统通过非辐射机制净化有机废水综述

IF 6.1 2区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL
Yunxin Huang, Shouyan Zhao, Keyu Chen, Baocheng Huang, Rencun Jin
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引用次数: 0

摘要

工业和农业部门产生的大量难处理有机废水对水生态系统和人类健康构成了严重威胁,因此有必要探索具有成本效益和高效的去除技术。过硫酸盐在各种催化剂的活化下可产生氧化物,在修复有机废水方面具有广阔的前景。近年来,大量研究揭示了过硫酸盐可以很容易地分解成非自由基,对污染物具有高选择性,在复杂的废水环境中性能稳定。然而,非自由基的识别难题和催化机理的不明确阻碍了它的进一步应用。本文对基于过硫酸盐的异相催化体系中的非自由基氧化研究进展进行了评述。总结了三种非自由基氧化途径(即单线态氧、电子转移和高价金属氧化物)的主要进展和现有挑战,并阐述了影响非自由基产生的关键因素。还进一步讨论了非自由基氧化系统的工程方面,并展望了该技术在废水处理中的未来前景。本综述旨在弥补当前研究与未来需求之间的知识差距。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A review of persulfate-based advanced oxidation system for decontaminating organic wastewater via non-radical regime

A review of persulfate-based advanced oxidation system for decontaminating organic wastewater via non-radical regime

The large amount of refractory organic wastewater produced from industry and agriculture sectors poses a significant threat to both water ecosystems and human health, necessitating the exploration of cost-efficient and efficacious removal techniques. Persulfate, when activated by various catalysts, can produce oxidative species, demonstrating promising potential in remediating organic wastewater. In recent years, numerous studies have unveiled that persulfate can be readily decomposed into nonradicals, which exhibits high selectivity toward pollutants and robust performance in complex wastewater environments. However, the challenges in identifying non-radicals and the unclear catalytic mechanism hinder its further application. This paper critically reviews the research progress on non-radical oxidation in persulfate-based heterogeneous catalytic system. The main advancements and existing challenges in three non-radical oxidation pathways, i.e., singlet oxygen, electron transfer, and high-valent metal oxides, are summarized, and the key factors influencing the production of nonradicals are elaborated. The engineering aspects of non-radical oxidation system are further discussed, and the future prospects of this technology in wastewater treatment are envisaged. This review aims to bridge the knowledge gaps between current research and future requirements.

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来源期刊
Frontiers of Environmental Science & Engineering
Frontiers of Environmental Science & Engineering ENGINEERING, ENVIRONMENTAL-ENVIRONMENTAL SCIENCES
CiteScore
10.90
自引率
12.50%
发文量
988
审稿时长
6.1 months
期刊介绍: Frontiers of Environmental Science & Engineering (FESE) is an international journal for researchers interested in a wide range of environmental disciplines. The journal''s aim is to advance and disseminate knowledge in all main branches of environmental science & engineering. The journal emphasizes papers in developing fields, as well as papers showing the interaction between environmental disciplines and other disciplines. FESE is a bi-monthly journal. Its peer-reviewed contents consist of a broad blend of reviews, research papers, policy analyses, short communications, and opinions. Nonscheduled “special issue” and "hot topic", including a review article followed by a couple of related research articles, are organized to publish novel contributions and breaking results on all aspects of environmental field.
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