Marie Elis, Tim Tjardts, Josiah Ngenev Shondo, Ainura Aliyeva, Alexander Vahl, Ulrich Schürmann, Thomas Strunskus, Franz Faupel, Cenk Aktas, Lorenz Kienle, Salih Veziroglu
{"title":"单步制备 TiOx-CeOx 纳米粒子的新方法","authors":"Marie Elis, Tim Tjardts, Josiah Ngenev Shondo, Ainura Aliyeva, Alexander Vahl, Ulrich Schürmann, Thomas Strunskus, Franz Faupel, Cenk Aktas, Lorenz Kienle, Salih Veziroglu","doi":"10.1002/smsc.202400305","DOIUrl":null,"url":null,"abstract":"Mixed metal oxide (MMO) nanoparticles (NPs) are hybrids consisting of two or more nanoscale metal oxides. Advantages of MMO NPs over single metal oxides include improved catalytic activity, enhanced electrical and magnetic properties, and increased thermal stability due to the synergy of the different oxide components. This study presents a novel fabrication route for TiO<sub>2</sub>-CeO<sub>2</sub> NPs enriched with oxygen vacancies using a Haberland-type gas aggregation cluster source. The NPs, deposited from different segmented Ti/Ce targets under varying O<sub>2</sub> addition, were examined with respect to final composition, morphology, and Ti, Ce surface oxidation states. Particle formation mechanisms are proposed for the observed morphologies. Additionally, available O<sub>2</sub> during deposition and its impact on the formation of defective sites were investigated. Defective sites in TiO<sub>2</sub>-CeO<sub>2</sub> NPs were analyzed using transfer to X-ray photoelectron spectroscopy and transmission electron microscopy without contact to ambient oxygen. The incorporation of Ce to the target exhibits synergistic effects on the synthesis process. Segmented Ti/Ce targets enable the deposition of a broad range of mixed oxide NPs with diverse compositions and morphologies at considerably enhanced deposition rates, which is vital for practical applications. The presented fabrication approach is expected to be applicable for a broad variety of MMO NPs.","PeriodicalId":29791,"journal":{"name":"Small Science","volume":"393 1","pages":""},"PeriodicalIF":11.1000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A New Approach to Single-Step Fabrication of TiOx-CeOx Nanoparticles\",\"authors\":\"Marie Elis, Tim Tjardts, Josiah Ngenev Shondo, Ainura Aliyeva, Alexander Vahl, Ulrich Schürmann, Thomas Strunskus, Franz Faupel, Cenk Aktas, Lorenz Kienle, Salih Veziroglu\",\"doi\":\"10.1002/smsc.202400305\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Mixed metal oxide (MMO) nanoparticles (NPs) are hybrids consisting of two or more nanoscale metal oxides. Advantages of MMO NPs over single metal oxides include improved catalytic activity, enhanced electrical and magnetic properties, and increased thermal stability due to the synergy of the different oxide components. This study presents a novel fabrication route for TiO<sub>2</sub>-CeO<sub>2</sub> NPs enriched with oxygen vacancies using a Haberland-type gas aggregation cluster source. The NPs, deposited from different segmented Ti/Ce targets under varying O<sub>2</sub> addition, were examined with respect to final composition, morphology, and Ti, Ce surface oxidation states. Particle formation mechanisms are proposed for the observed morphologies. Additionally, available O<sub>2</sub> during deposition and its impact on the formation of defective sites were investigated. Defective sites in TiO<sub>2</sub>-CeO<sub>2</sub> NPs were analyzed using transfer to X-ray photoelectron spectroscopy and transmission electron microscopy without contact to ambient oxygen. The incorporation of Ce to the target exhibits synergistic effects on the synthesis process. Segmented Ti/Ce targets enable the deposition of a broad range of mixed oxide NPs with diverse compositions and morphologies at considerably enhanced deposition rates, which is vital for practical applications. The presented fabrication approach is expected to be applicable for a broad variety of MMO NPs.\",\"PeriodicalId\":29791,\"journal\":{\"name\":\"Small Science\",\"volume\":\"393 1\",\"pages\":\"\"},\"PeriodicalIF\":11.1000,\"publicationDate\":\"2024-09-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Small Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/smsc.202400305\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/smsc.202400305","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A New Approach to Single-Step Fabrication of TiOx-CeOx Nanoparticles
Mixed metal oxide (MMO) nanoparticles (NPs) are hybrids consisting of two or more nanoscale metal oxides. Advantages of MMO NPs over single metal oxides include improved catalytic activity, enhanced electrical and magnetic properties, and increased thermal stability due to the synergy of the different oxide components. This study presents a novel fabrication route for TiO2-CeO2 NPs enriched with oxygen vacancies using a Haberland-type gas aggregation cluster source. The NPs, deposited from different segmented Ti/Ce targets under varying O2 addition, were examined with respect to final composition, morphology, and Ti, Ce surface oxidation states. Particle formation mechanisms are proposed for the observed morphologies. Additionally, available O2 during deposition and its impact on the formation of defective sites were investigated. Defective sites in TiO2-CeO2 NPs were analyzed using transfer to X-ray photoelectron spectroscopy and transmission electron microscopy without contact to ambient oxygen. The incorporation of Ce to the target exhibits synergistic effects on the synthesis process. Segmented Ti/Ce targets enable the deposition of a broad range of mixed oxide NPs with diverse compositions and morphologies at considerably enhanced deposition rates, which is vital for practical applications. The presented fabrication approach is expected to be applicable for a broad variety of MMO NPs.
期刊介绍:
Small Science is a premium multidisciplinary open access journal dedicated to publishing impactful research from all areas of nanoscience and nanotechnology. It features interdisciplinary original research and focused review articles on relevant topics. The journal covers design, characterization, mechanism, technology, and application of micro-/nanoscale structures and systems in various fields including physics, chemistry, materials science, engineering, environmental science, life science, biology, and medicine. It welcomes innovative interdisciplinary research and its readership includes professionals from academia and industry in fields such as chemistry, physics, materials science, biology, engineering, and environmental and analytical science. Small Science is indexed and abstracted in CAS, DOAJ, Clarivate Analytics, ProQuest Central, Publicly Available Content Database, Science Database, SCOPUS, and Web of Science.