{"title":"铬含量对用于固体氧化物燃料电池互连器件的粉末冶金铁素体不锈钢的机械、氧化和电气性能的影响","authors":"Ziqi Liu, Ruoxi Song, Shuangfei Yan, Di Chen, Chen Ou, Chenyu Wang, Qingqing Pan, Jingguang Peng","doi":"10.1007/s11665-024-10016-5","DOIUrl":null,"url":null,"abstract":"<p>This study aims to investigate the influence of Cr content on the high-temperature mechanical, oxidation, and electrical properties of powder metallurgy ferritic stainless steel for solid oxide fuel cell (SOFC) interconnect. To achieve this objective, ferritic stainless steel water-atomized powders with different Cr content were first compacted and then sintered at 1380 °C for 2 h under hydrogen atmosphere. The properties were evaluated through high-temperature tensile tests at 800 °C, oxidation tests, and area-specific resistance (ASR) measurements. Microstructural characterization was conducted using x-ray diffraction (XRD), scanning electron microscope (SEM) with energy-dispersive spectroscope (EDS). The results indicated that with an increase in Cr content, the strength of the powder metallurgy ferritic stainless steel specimens increased, while the elongation decreased at 800°C. Additionally, oxidation mass gain decreased, and ASR decreased. Commercially available ZMG232 ferritic stainless steel was employed for high-temperature mechanical, oxidation, and electrical properties comparison. Compared to ZMG232, the high-temperature yield strength and tensile strength of powder metallurgy ferritic stainless steel specimens were higher with 22 wt.% and 26 wt.% Cr content. And with 17 wt.% Cr content, there was a significant difference in oxidation mass gain and ASR. However, with 22 wt.% and 26 wt.% Cr content, oxidation mass gain and ASR were relatively close, indicated that the high Cr content powder metallurgy ferritic stainless steel in this study can be an alternative to the commercially available ZMG232 ferritic stainless steel.</p>","PeriodicalId":644,"journal":{"name":"Journal of Materials Engineering and Performance","volume":"34 1","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Cr Content on the Mechanical, Oxidation, and Electrical Properties of Powder Metallurgy Ferritic Stainless Steel for Solid Oxide Fuel Cell Interconnect\",\"authors\":\"Ziqi Liu, Ruoxi Song, Shuangfei Yan, Di Chen, Chen Ou, Chenyu Wang, Qingqing Pan, Jingguang Peng\",\"doi\":\"10.1007/s11665-024-10016-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study aims to investigate the influence of Cr content on the high-temperature mechanical, oxidation, and electrical properties of powder metallurgy ferritic stainless steel for solid oxide fuel cell (SOFC) interconnect. To achieve this objective, ferritic stainless steel water-atomized powders with different Cr content were first compacted and then sintered at 1380 °C for 2 h under hydrogen atmosphere. The properties were evaluated through high-temperature tensile tests at 800 °C, oxidation tests, and area-specific resistance (ASR) measurements. Microstructural characterization was conducted using x-ray diffraction (XRD), scanning electron microscope (SEM) with energy-dispersive spectroscope (EDS). The results indicated that with an increase in Cr content, the strength of the powder metallurgy ferritic stainless steel specimens increased, while the elongation decreased at 800°C. Additionally, oxidation mass gain decreased, and ASR decreased. Commercially available ZMG232 ferritic stainless steel was employed for high-temperature mechanical, oxidation, and electrical properties comparison. Compared to ZMG232, the high-temperature yield strength and tensile strength of powder metallurgy ferritic stainless steel specimens were higher with 22 wt.% and 26 wt.% Cr content. And with 17 wt.% Cr content, there was a significant difference in oxidation mass gain and ASR. However, with 22 wt.% and 26 wt.% Cr content, oxidation mass gain and ASR were relatively close, indicated that the high Cr content powder metallurgy ferritic stainless steel in this study can be an alternative to the commercially available ZMG232 ferritic stainless steel.</p>\",\"PeriodicalId\":644,\"journal\":{\"name\":\"Journal of Materials Engineering and Performance\",\"volume\":\"34 1\",\"pages\":\"\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-09-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Engineering and Performance\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s11665-024-10016-5\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Engineering and Performance","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s11665-024-10016-5","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
本研究旨在探讨铬含量对用于固体氧化物燃料电池(SOFC)互连器件的粉末冶金铁素体不锈钢的高温机械、氧化和电气性能的影响。为实现这一目标,首先压制了不同含铬量的铁素体不锈钢水原子化粉末,然后在氢气环境下于 1380 °C 下烧结 2 小时。通过 800 °C 高温拉伸试验、氧化试验和特定区域电阻(ASR)测量,对其性能进行了评估。使用 X 射线衍射 (XRD)、扫描电子显微镜 (SEM) 和能量色散光谱仪 (EDS) 进行了微结构表征。结果表明,随着铬含量的增加,粉末冶金铁素体不锈钢试样的强度提高了,而 800°C 时的伸长率降低了。此外,氧化增量减少,ASR 下降。采用市售的 ZMG232 铁素体不锈钢进行高温机械、氧化和电气性能比较。与 ZMG232 相比,铬含量为 22 重量% 和 26 重量% 的粉末冶金铁素体不锈钢试样的高温屈服强度和抗拉强度更高。而当铬含量为 17 重量%时,氧化增量和 ASR 有显著差异。然而,当铬含量为 22 重量%和 26 重量%时,氧化质量增益和 ASR 相对接近,这表明本研究中的高铬含量粉末冶金铁素体不锈钢可替代市售的 ZMG232 铁素体不锈钢。
Influence of Cr Content on the Mechanical, Oxidation, and Electrical Properties of Powder Metallurgy Ferritic Stainless Steel for Solid Oxide Fuel Cell Interconnect
This study aims to investigate the influence of Cr content on the high-temperature mechanical, oxidation, and electrical properties of powder metallurgy ferritic stainless steel for solid oxide fuel cell (SOFC) interconnect. To achieve this objective, ferritic stainless steel water-atomized powders with different Cr content were first compacted and then sintered at 1380 °C for 2 h under hydrogen atmosphere. The properties were evaluated through high-temperature tensile tests at 800 °C, oxidation tests, and area-specific resistance (ASR) measurements. Microstructural characterization was conducted using x-ray diffraction (XRD), scanning electron microscope (SEM) with energy-dispersive spectroscope (EDS). The results indicated that with an increase in Cr content, the strength of the powder metallurgy ferritic stainless steel specimens increased, while the elongation decreased at 800°C. Additionally, oxidation mass gain decreased, and ASR decreased. Commercially available ZMG232 ferritic stainless steel was employed for high-temperature mechanical, oxidation, and electrical properties comparison. Compared to ZMG232, the high-temperature yield strength and tensile strength of powder metallurgy ferritic stainless steel specimens were higher with 22 wt.% and 26 wt.% Cr content. And with 17 wt.% Cr content, there was a significant difference in oxidation mass gain and ASR. However, with 22 wt.% and 26 wt.% Cr content, oxidation mass gain and ASR were relatively close, indicated that the high Cr content powder metallurgy ferritic stainless steel in this study can be an alternative to the commercially available ZMG232 ferritic stainless steel.
期刊介绍:
ASM International''s Journal of Materials Engineering and Performance focuses on solving day-to-day engineering challenges, particularly those involving components for larger systems. The journal presents a clear understanding of relationships between materials selection, processing, applications and performance.
The Journal of Materials Engineering covers all aspects of materials selection, design, processing, characterization and evaluation, including how to improve materials properties through processes and process control of casting, forming, heat treating, surface modification and coating, and fabrication.
Testing and characterization (including mechanical and physical tests, NDE, metallography, failure analysis, corrosion resistance, chemical analysis, surface characterization, and microanalysis of surfaces, features and fractures), and industrial performance measurement are also covered