合成用于纺织品染色的 4-硝基苯胺偶氮染料以及使用化学改性甘蔗渣吸附剂去除污水中的偶氮染料

IF 2.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES
Ghada Kadry, Heba A. El-Gawad
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引用次数: 0

摘要

本研究探讨了 4-硝基苯胺作为新型重氮组分合成偶氮染料的潜力,突出了该研究的新颖性。通过重氮化 4-硝基苯胺,然后分别与水杨酸和邻苯二酚偶联,制备了两种新的偶氮染料,分别命名为 4-(4-硝基苯偶氮)水杨酸(SS)和 4-(4-硝基苯偶氮)邻苯二酚(OH)。傅立叶变换红外光谱和其他分析技术证实了这些染料在应用于棉、羊毛、腈纶和涤纶织物前后的结构完整性。这些染料在棉织物上表现出最佳的着色力(K/S)和牢度特性。随着温度的升高,染料在棉纤维上的耗尽和固着情况有所改善,在 95 °C 时达到最佳效率(SS 为 83.92% 和 80.34%,OH 为 89% 和 84.36%)。此外,该研究还探讨了一种从纺织废水中去除染料的可持续方法。甘蔗渣是一种成本效益高且环保的吸附剂,经过硫酸预处理(优于甲醛)后,可有效去除废水中的染料。在最佳条件下(2.5 克、50 ppm、pH 值 9、200 转/分、120 分钟),这种处理方法的去除率高达 99.34%。吸附表现出郎穆尔等温线和假二阶动力学的特征。扩散研究表明,颗粒内扩散是控制吸附速率的步骤,而薄膜扩散则很可能控制吸附。回归模型显示,工艺因素与染料去除率之间的 R2 值为 93.89%。通过处理来自埃及一家工厂的实际高污染纺织废水,进一步验证了该方法的有效性。在最佳条件下,甘蔗渣处理可有效去除染料(近 98.8%),这证明了其在多次染料去除循环后的可再利用性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis of Azo Dyes Derived from 4-Nitroaniline for Textile Coloration and Their Removal from Effluents Using Chemically Modified Sugarcane Bagasse Adsorbent

Synthesis of Azo Dyes Derived from 4-Nitroaniline for Textile Coloration and Their Removal from Effluents Using Chemically Modified Sugarcane Bagasse Adsorbent

Synthesis of Azo Dyes Derived from 4-Nitroaniline for Textile Coloration and Their Removal from Effluents Using Chemically Modified Sugarcane Bagasse Adsorbent

This inspection explores the potential of 4-nitroaniline’s potential as a novel diazo component in synthesizing azo dyes, highlighting the research’s novelty. Two new azo dyes, designated 4-(4-nitrophenylazo) salicylic acid (SS) and 4-(4-nitrophenylazo) catechol (OH), were prepared by diazotization of 4-nitroaniline followed by coupling with salicylic acid and catechol, respectively. Fourier transform infrared spectroscopy and other analytical techniques confirmed the structural integrity of the dyes before and after application to cotton, wool, acrylic, and polyester fabrics. The dyes exhibited the best color strength (K/S) and fastness properties on cotton. The exhaustion and fixation of the dyes onto cotton fibers improved with increasing temperature, reaching optimal efficiencies (83.92 and 80.34% for SS and 89 and 84.36% for OH) at 95 °C. Furthermore, the study investigates a sustainable method for removing the dyes from textile wastewater. Sugarcane bagasse, a cost-effectiveness and environmentally friendly sorbent, achieved effectual dye elimination from wastewater after sulfuric acid pre-treatment (superior to formaldehyde). This treatment achieved a remarkable 99.34% removal efficiency under optimal conditions (2.5 g, 50 ppm, pH 9, 200 rpm, 120 min). Adsorption exhibited characteristics of both Langmuir isotherm and pseudo-second order kinetics. Diffusion studies revealed intraparticle diffusion as the rate-controlling step, with film diffusion likely governing the adsorption. Regression modeling yielded an R2 of 93.89% between process factors and dye removal. The effectiveness was further validated by treating real-world, highly polluted textile wastewater obtained from an Egyptian factory. The sugarcane bagasse treatment effectively removed dyes (almost 98.8%) under optimal conditions, demonstrating its reusability after multiple dye-removal cycles.

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来源期刊
Fibers and Polymers
Fibers and Polymers 工程技术-材料科学:纺织
CiteScore
3.90
自引率
8.00%
发文量
267
审稿时长
3.9 months
期刊介绍: -Chemistry of Fiber Materials, Polymer Reactions and Synthesis- Physical Properties of Fibers, Polymer Blends and Composites- Fiber Spinning and Textile Processing, Polymer Physics, Morphology- Colorants and Dyeing, Polymer Analysis and Characterization- Chemical Aftertreatment of Textiles, Polymer Processing and Rheology- Textile and Apparel Science, Functional Polymers
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