作为碳-聚合物复合双极板的新型次导电填料的碳雪凝胶

IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY
Priyanka Sharma, Abdurrahman Bilican, Wolfgang Schmidt, Olof Gutowski, Ann-Christin Dippel, Kimberley Matschuk, Lukas Kopietz, Claudia Weidenthaler
{"title":"作为碳-聚合物复合双极板的新型次导电填料的碳雪凝胶","authors":"Priyanka Sharma, Abdurrahman Bilican, Wolfgang Schmidt, Olof Gutowski, Ann-Christin Dippel, Kimberley Matschuk, Lukas Kopietz, Claudia Weidenthaler","doi":"10.1002/batt.202400316","DOIUrl":null,"url":null,"abstract":"The current research explores the potential of carbon xerogel as a conductive filler in bipolar plates. The composites comprise graphite as the primary conductive filler and polypropylene as the binder. Carbon xerogel is introduced as a minor conductive filler, and its performance is compared with commercial carbon black. Both nanocarbons exhibit resemblances in microstructure, texture, and surface carbon chemistry. Through‐plane conductivity measurements reveal enhanced electrical conductivity upon replacing a fraction of graphite with either nanofiller. Cross‐sectional analyses of the plates employing computed tomography based on X‐ray diffraction and phase contrasts indicate that the observed electrical conductivity difference stems from reduced trapped air during production and the distribution of the minor filler particles. Given the similarities between carbon xerogel and the reference nanofiller, this study introduces the innovative concept of employing carbon xerogel as a filler for conductive bipolar plates.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"32 1","pages":""},"PeriodicalIF":5.1000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Carbon Xerogel as a Novel Minor Conductive Filler for Carbon‐Polymer Composite Bipolar Plates\",\"authors\":\"Priyanka Sharma, Abdurrahman Bilican, Wolfgang Schmidt, Olof Gutowski, Ann-Christin Dippel, Kimberley Matschuk, Lukas Kopietz, Claudia Weidenthaler\",\"doi\":\"10.1002/batt.202400316\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The current research explores the potential of carbon xerogel as a conductive filler in bipolar plates. The composites comprise graphite as the primary conductive filler and polypropylene as the binder. Carbon xerogel is introduced as a minor conductive filler, and its performance is compared with commercial carbon black. Both nanocarbons exhibit resemblances in microstructure, texture, and surface carbon chemistry. Through‐plane conductivity measurements reveal enhanced electrical conductivity upon replacing a fraction of graphite with either nanofiller. Cross‐sectional analyses of the plates employing computed tomography based on X‐ray diffraction and phase contrasts indicate that the observed electrical conductivity difference stems from reduced trapped air during production and the distribution of the minor filler particles. Given the similarities between carbon xerogel and the reference nanofiller, this study introduces the innovative concept of employing carbon xerogel as a filler for conductive bipolar plates.\",\"PeriodicalId\":132,\"journal\":{\"name\":\"Batteries & Supercaps\",\"volume\":\"32 1\",\"pages\":\"\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-08-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Batteries & Supercaps\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/batt.202400316\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Batteries & Supercaps","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/batt.202400316","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0

摘要

目前的研究探索了碳异凝胶作为双极板导电填料的潜力。复合材料包括作为主要导电填料的石墨和作为粘合剂的聚丙烯。碳异凝胶作为次要导电填料被引入,其性能与商用炭黑进行了比较。这两种纳米碳在微观结构、质地和表面碳化学性质方面都有相似之处。通面电导率测量结果表明,用其中一种纳米填料取代一部分石墨后,电导率会增强。利用基于 X 射线衍射和相位对比的计算机断层扫描技术对板材进行的横截面分析表明,观察到的导电性差异源于生产过程中残留空气的减少和次要填料颗粒的分布。鉴于碳异凝胶与参考纳米填料之间的相似性,本研究提出了采用碳异凝胶作为导电双极板填料的创新概念。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Carbon Xerogel as a Novel Minor Conductive Filler for Carbon‐Polymer Composite Bipolar Plates
The current research explores the potential of carbon xerogel as a conductive filler in bipolar plates. The composites comprise graphite as the primary conductive filler and polypropylene as the binder. Carbon xerogel is introduced as a minor conductive filler, and its performance is compared with commercial carbon black. Both nanocarbons exhibit resemblances in microstructure, texture, and surface carbon chemistry. Through‐plane conductivity measurements reveal enhanced electrical conductivity upon replacing a fraction of graphite with either nanofiller. Cross‐sectional analyses of the plates employing computed tomography based on X‐ray diffraction and phase contrasts indicate that the observed electrical conductivity difference stems from reduced trapped air during production and the distribution of the minor filler particles. Given the similarities between carbon xerogel and the reference nanofiller, this study introduces the innovative concept of employing carbon xerogel as a filler for conductive bipolar plates.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信