同时进行海水溶解无机碳(DIC)浓度和稳定同位素比值(δ13C-DIC)的船上分析

IF 2.1 3区 地球科学 Q2 LIMNOLOGY
Zhentao Sun, Xinyu Li, Zhangxian Ouyang, Charles Featherstone, Eliot A. Atekwana, Najid Hussain, Wei‐Jun Cai
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引用次数: 0

摘要

溶解无机碳(DIC)及其稳定碳同位素(δ13C-DIC)是研究水生碳循环和量化海洋人为碳累积率的宝贵参数。然而,由于传统的同位素分析耗费大量人力物力,且仅限于陆上实验室,因此仅有 15%或更少的巡航样本进行过 δ13C-DIC 分析,这对耦合参数的潜力尚未得到充分利用。在此,我们提高了分析精度,并报告了一种基于空腔环降光谱(CRDS)的自动化、高效和高精度的船载 DIC 和 δ13C-DIC 分析方法。我们还引入了一套稳定的内部标准,以确保 DIC 和 δ13C-DIC 测量的准确性和一致性,尤其是在长期巡航中。利用这种方法,我们在 2022 年夏季沿北美东大洋边缘进行了为期 40 天的巡航,分析了 1600 多个离散海水样本,这是首次在任何海洋考察船上收集δ13C-DIC 的大型数据集。我们评估了该方法的不确定性,DIC 浓度为 1.2 μmol kg-1,δ13C-DIC 值为 0.03‰(1σ)。机载 DIC 浓度分析的实验室间比较显示,CRDS 和基于库仑计的结果之间的平均偏差为 2.0 ± 3.8 μmol kg-1。深海数据中δ13C-DIC 的交叉验证显示平均差异仅为 -0.03‰ ± 0.07‰,强调了与历史数据的一致性。讨论了在水生生物地球化学中的潜在应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Simultaneous onboard analysis of seawater dissolved inorganic carbon (DIC) concentration and stable isotope ratio (δ13C‐DIC)
Dissolved inorganic carbon (DIC) and its stable carbon isotope (δ13C‐DIC) are valuable parameters for studying the aquatic carbon cycle and quantifying ocean anthropogenic carbon accumulation rates. However, the potential of this coupled pair is underexploited as only 15% or less of cruise samples have been analyzed for δ13C‐DIC because the traditional isotope analysis is labor‐intensive and restricted to onshore laboratories. Here, we improved the analytical precision and reported the protocol of an automated, efficient, and high‐precision method for ship‐based DIC and δ13C‐DIC analysis based on cavity ring‐down spectroscopy (CRDS). We also introduced a set of stable in‐house standards to ensure accurate and consistent DIC and δ13C‐DIC measurements, especially on prolonged cruises. With this method, we analyzed over 1600 discrete seawater samples over a 40‐d cruise along the North American eastern ocean margin in summer 2022, representing the first effort to collect a large dataset of δ13C‐DIC onboard of any oceanographic expedition. We evaluated the method's uncertainty, which was 1.2 μmol kg−1 for the DIC concentration and 0.03‰ for the δ13C‐DIC value (1σ). An interlaboratory comparison of onboard DIC concentration analysis revealed an average offset of 2.0 ± 3.8 μmol kg−1 between CRDS and the coulometry‐based results. The cross‐validation of δ13C‐DIC in the deep‐ocean data exhibited a mean difference of only −0.03‰ ± 0.07‰, emphasizing the consistency with historical data. Potential applications in aquatic biogeochemistry are discussed.
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来源期刊
CiteScore
4.80
自引率
3.70%
发文量
56
审稿时长
3 months
期刊介绍: Limnology and Oceanography: Methods (ISSN 1541-5856) is a companion to ASLO''s top-rated journal Limnology and Oceanography, and articles are held to the same high standards. In order to provide the most rapid publication consistent with high standards, Limnology and Oceanography: Methods appears in electronic format only, and the entire submission and review system is online. Articles are posted as soon as they are accepted and formatted for publication. Limnology and Oceanography: Methods will consider manuscripts whose primary focus is methodological, and that deal with problems in the aquatic sciences. Manuscripts may present new measurement equipment, techniques for analyzing observations or samples, methods for understanding and interpreting information, analyses of metadata to examine the effectiveness of approaches, invited and contributed reviews and syntheses, and techniques for communicating and teaching in the aquatic sciences.
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