Yue Pan, Chunhua Zhao, Ruirui Wang, Mingjie Zhu, Wenchang Zhuang and Qintang Li
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引用次数: 0
摘要
离子液体(ILs)的结构会影响其理化性质,从而决定其作为自组装介质的性能。在本研究中,我们重点研究了烷基离子液体(AILs)的阴离子效应。研究了阳离子表面活性剂 1-十六烷基-3-甲基溴化咪唑鎓(C16mimBr)在含有 1-乙基-3-甲基咪唑阳离子和不同阴离子(包括硝酸盐、乙基硫酸盐、双(三氟甲基磺酰基)亚胺和四氟硼酸盐)的咪唑 AILs 中的聚集行为。利用表面张力测量法确定了 C16mimBr 的表面吸附参数,AIL 中的临界胶束化浓度值因其内聚能的不同而不同。随着 C16mimBr 浓度的增加,出现了胶束和层状各向同性液晶相。利用小角 X 射线散射、偏光光学显微镜、流变学和差示扫描量热法测定了聚集体的结构和性质。分析和讨论了 AIL 的阴离子对聚集体的相行为、结构和性质的影响。层状各向同性液晶显示出良好的导电性,电化学阻抗光谱表征也证实了这一点。我们的研究结果加深了人们对作为自组装介质的液晶的结构效应的理解,并有助于可定制溶剂的设计。
Self-assembly of the imidazolium surfactant in aprotic ionic liquids. The anion effect of aprotic ionic liquids†
The structure of ionic liquids (ILs) has an influence on their physiochemical properties, determining their performance as self-assembly media. In this study, we focus on the anion effect of aprotic ionic liquids (AILs). The aggregation behaviours of the cationic surfactant 1-hexadecyl-3-methylimidazolium bromide (C16mimBr) have been investigated in the imidazolium AILs with the 1-ethyl-3-methyl imidazolium cation and different anions, including nitrate, ethylsulfate, bis(trifluoromethylsulfonyl) imide and tetrafluoroborate. Surface adsorption parameters of C16mimBr were determined using surface tension measurements, and the critical micellization concentration values in AILs vary for their different cohesive energy. The micellar and lamellar lyotropic liquid crystal phases emerge with the increase of C16mimBr concentrations. The structure and properties of aggregates were determined using small angle X-ray scattering, polarized optical microscopy, rheology and differential scanning calorimetry. The anion effects of AILs on the phase behaviours and structure and properties of aggregates were analysed and discussed. The lamellar lyotropic liquid crystals have shown good conductivity, as confirmed by electrochemical impedance spectroscopy characterization. Our results enhance the understanding of the structure effect of ILs as self-assembly media and contribute to the design of tailorable solvents.