Qisong Li, Yifei Ma, Ao Li, Yanfeng Gao, Shaopei Jia, Qian Zhang, Xiaozhe Cheng, Zhixin Wang, Yunchao Mu, Quan Huang
{"title":"碳化硅粉末微观形貌对火花等离子烧结法制备的硅/碳化硅陶瓷性能的影响","authors":"Qisong Li, Yifei Ma, Ao Li, Yanfeng Gao, Shaopei Jia, Qian Zhang, Xiaozhe Cheng, Zhixin Wang, Yunchao Mu, Quan Huang","doi":"10.1111/ijac.14904","DOIUrl":null,"url":null,"abstract":"To solve the problem that Si was volatile and dense Si/SiC ceramics were difficult to achieve by spark plasma sintering (SPS) under a low sintering temperature and pressure, three kinds of SiC powders were used for particle grading and then ball‐milled with different time to further change and regulate their particle size and morphology, and finally nearly dense Si/SiC ceramics were prepared by SPS. The effect of milling time on particle size, morphology, tap density, phase, and microstructure of the SiC powders, as well as on bulk density, microhardness, thermal conductivity, phase, and microstructure of the Si/SiC ceramic, was researched. When the mixed SiC powders were ball‐milled for 12 min, the bulk density, microhardness, and thermal conductivity of Si/SiC ceramic were 2.96 g/cm<jats:sup>3</jats:sup>, 22.95 GPa, and 152.84 W/(m K), respectively. Ball milling changed the particle gradation and micro‐powder morphology and then affected the powder particle stacking state. Forming continuous pore channels was conducive for the volatile liquid Si to flowing and filling pores in a short time, resulting in denser Si/SiC ceramics at a lower sintering temperature and pressure. This study was useful for the preparation of ceramics containing volatile liquid phase by SPS.","PeriodicalId":13903,"journal":{"name":"International Journal of Applied Ceramic Technology","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of the SiC powder microscopic morphology on properties of Si/SiC ceramics prepared by spark plasma sintering\",\"authors\":\"Qisong Li, Yifei Ma, Ao Li, Yanfeng Gao, Shaopei Jia, Qian Zhang, Xiaozhe Cheng, Zhixin Wang, Yunchao Mu, Quan Huang\",\"doi\":\"10.1111/ijac.14904\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"To solve the problem that Si was volatile and dense Si/SiC ceramics were difficult to achieve by spark plasma sintering (SPS) under a low sintering temperature and pressure, three kinds of SiC powders were used for particle grading and then ball‐milled with different time to further change and regulate their particle size and morphology, and finally nearly dense Si/SiC ceramics were prepared by SPS. The effect of milling time on particle size, morphology, tap density, phase, and microstructure of the SiC powders, as well as on bulk density, microhardness, thermal conductivity, phase, and microstructure of the Si/SiC ceramic, was researched. When the mixed SiC powders were ball‐milled for 12 min, the bulk density, microhardness, and thermal conductivity of Si/SiC ceramic were 2.96 g/cm<jats:sup>3</jats:sup>, 22.95 GPa, and 152.84 W/(m K), respectively. Ball milling changed the particle gradation and micro‐powder morphology and then affected the powder particle stacking state. Forming continuous pore channels was conducive for the volatile liquid Si to flowing and filling pores in a short time, resulting in denser Si/SiC ceramics at a lower sintering temperature and pressure. This study was useful for the preparation of ceramics containing volatile liquid phase by SPS.\",\"PeriodicalId\":13903,\"journal\":{\"name\":\"International Journal of Applied Ceramic Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-08-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Applied Ceramic Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1111/ijac.14904\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Ceramic Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1111/ijac.14904","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
摘要
为了解决硅易挥发、低烧结温度和压力下火花等离子体烧结(SPS)难以制备出致密的 Si/SiC 陶瓷的问题,采用三种 SiC 粉末进行颗粒分级,然后用不同时间的球磨进一步改变和调节其粒度和形貌,最终用 SPS 制备出近乎致密的 Si/SiC 陶瓷。研究了研磨时间对 SiC 粉末的粒度、形貌、敲击密度、相和微观结构的影响,以及对 Si/SiC 陶瓷的体积密度、显微硬度、热导率、相和微观结构的影响。将混合碳化硅粉末球磨 12 分钟后,Si/SiC 陶瓷的体积密度、显微硬度和热导率分别为 2.96 g/cm3、22.95 GPa 和 152.84 W/(m K)。球磨改变了颗粒级配和微粉形态,进而影响了粉末颗粒的堆积状态。形成连续的孔道有利于挥发性液态 Si 在短时间内流动并填充孔隙,从而在较低的烧结温度和压力下获得致密的 Si/SiC 陶瓷。这项研究有助于利用 SPS 制备含有挥发性液相的陶瓷。
Effect of the SiC powder microscopic morphology on properties of Si/SiC ceramics prepared by spark plasma sintering
To solve the problem that Si was volatile and dense Si/SiC ceramics were difficult to achieve by spark plasma sintering (SPS) under a low sintering temperature and pressure, three kinds of SiC powders were used for particle grading and then ball‐milled with different time to further change and regulate their particle size and morphology, and finally nearly dense Si/SiC ceramics were prepared by SPS. The effect of milling time on particle size, morphology, tap density, phase, and microstructure of the SiC powders, as well as on bulk density, microhardness, thermal conductivity, phase, and microstructure of the Si/SiC ceramic, was researched. When the mixed SiC powders were ball‐milled for 12 min, the bulk density, microhardness, and thermal conductivity of Si/SiC ceramic were 2.96 g/cm3, 22.95 GPa, and 152.84 W/(m K), respectively. Ball milling changed the particle gradation and micro‐powder morphology and then affected the powder particle stacking state. Forming continuous pore channels was conducive for the volatile liquid Si to flowing and filling pores in a short time, resulting in denser Si/SiC ceramics at a lower sintering temperature and pressure. This study was useful for the preparation of ceramics containing volatile liquid phase by SPS.
期刊介绍:
The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas:
Nanotechnology applications;
Ceramic Armor;
Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors);
Ceramic Matrix Composites;
Functional Materials;
Thermal and Environmental Barrier Coatings;
Bioceramic Applications;
Green Manufacturing;
Ceramic Processing;
Glass Technology;
Fiber optics;
Ceramics in Environmental Applications;
Ceramics in Electronic, Photonic and Magnetic Applications;