{"title":"通过水热合成和聚吡咯增强技术调节混合金属铁氧体的光学、电学、结构和光催化活性","authors":"Amira Alazmi","doi":"10.1016/j.ceramint.2024.09.171","DOIUrl":null,"url":null,"abstract":"<p>This work describes the synthesis, characterization, and photocatalytic evaluation of a polypyrrole-reinforced zinc-nickel mixed metal ferrite (PPy@ Zn<sub>0.5</sub>Ni<sub>0.5</sub>Fe<sub>2</sub>O<sub>4</sub>) nanohybrid. A facile hydrothermal process is employed to synthesize the nanostructured zinc-nickel mixed metal ferrite (ZNF), and in situ oxidative polymerization is utilized to create the PPy nanohybrid. In this nanohybrid, PPy plays multiple roles: preventing charge recombination, reducing photocorrosion, mitigating particle aggregation in ZNF, and enhancing charge transfer and visible light absorption. The combined electron-capturing ability, intrinsic conductivity, and extensive π-conjugation of PPy, along with the magnetic nature of ZNF, render the PPy@ZNF catalyst highly efficient. The results of photoluminescence, impedance, and UV/Vis analysis confirm that PPy plays a critical role in enhancing photocatalytic performance by facilitating charge transfer and extending visible-light absorption. In practical environmental applications, the PPy@ZNF nanohybrid demonstrated superior photocatalytic activity compared to ZNF alone, degrading 98.5% of malachite green dye under W-lamp light within 80 minutes, with a rate constant of 0.031 min<sup>-1</sup>. Scavenger and cyclic experiments identified the active species involved in dye degradation and assessed the reusability of the nanohybrid. Extensive testing revealed the optimal conditions for photocatalytic efficiency; the considered variables included light intensity, catalyst dose, dye concentration, temperature, irradiation time, and pH. These findings suggest that the PPy-reinforced ZNF nanohybrid offers cost-effectiveness, magnetic recoverability, structural stability, and high efficacy as a visible light-driven catalyst, making it a promising candidate for diverse environmental remediation applications.</p>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":null,"pages":null},"PeriodicalIF":5.1000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Tuning the Optical, Electrical, Structural and Photocatalytic Activities of Mixed Metal Ferrite by Hydrothermal Synthesis and Polypyrrole Reinforcement\",\"authors\":\"Amira Alazmi\",\"doi\":\"10.1016/j.ceramint.2024.09.171\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This work describes the synthesis, characterization, and photocatalytic evaluation of a polypyrrole-reinforced zinc-nickel mixed metal ferrite (PPy@ Zn<sub>0.5</sub>Ni<sub>0.5</sub>Fe<sub>2</sub>O<sub>4</sub>) nanohybrid. A facile hydrothermal process is employed to synthesize the nanostructured zinc-nickel mixed metal ferrite (ZNF), and in situ oxidative polymerization is utilized to create the PPy nanohybrid. In this nanohybrid, PPy plays multiple roles: preventing charge recombination, reducing photocorrosion, mitigating particle aggregation in ZNF, and enhancing charge transfer and visible light absorption. The combined electron-capturing ability, intrinsic conductivity, and extensive π-conjugation of PPy, along with the magnetic nature of ZNF, render the PPy@ZNF catalyst highly efficient. The results of photoluminescence, impedance, and UV/Vis analysis confirm that PPy plays a critical role in enhancing photocatalytic performance by facilitating charge transfer and extending visible-light absorption. In practical environmental applications, the PPy@ZNF nanohybrid demonstrated superior photocatalytic activity compared to ZNF alone, degrading 98.5% of malachite green dye under W-lamp light within 80 minutes, with a rate constant of 0.031 min<sup>-1</sup>. Scavenger and cyclic experiments identified the active species involved in dye degradation and assessed the reusability of the nanohybrid. Extensive testing revealed the optimal conditions for photocatalytic efficiency; the considered variables included light intensity, catalyst dose, dye concentration, temperature, irradiation time, and pH. These findings suggest that the PPy-reinforced ZNF nanohybrid offers cost-effectiveness, magnetic recoverability, structural stability, and high efficacy as a visible light-driven catalyst, making it a promising candidate for diverse environmental remediation applications.</p>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1016/j.ceramint.2024.09.171\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.ceramint.2024.09.171","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Tuning the Optical, Electrical, Structural and Photocatalytic Activities of Mixed Metal Ferrite by Hydrothermal Synthesis and Polypyrrole Reinforcement
This work describes the synthesis, characterization, and photocatalytic evaluation of a polypyrrole-reinforced zinc-nickel mixed metal ferrite (PPy@ Zn0.5Ni0.5Fe2O4) nanohybrid. A facile hydrothermal process is employed to synthesize the nanostructured zinc-nickel mixed metal ferrite (ZNF), and in situ oxidative polymerization is utilized to create the PPy nanohybrid. In this nanohybrid, PPy plays multiple roles: preventing charge recombination, reducing photocorrosion, mitigating particle aggregation in ZNF, and enhancing charge transfer and visible light absorption. The combined electron-capturing ability, intrinsic conductivity, and extensive π-conjugation of PPy, along with the magnetic nature of ZNF, render the PPy@ZNF catalyst highly efficient. The results of photoluminescence, impedance, and UV/Vis analysis confirm that PPy plays a critical role in enhancing photocatalytic performance by facilitating charge transfer and extending visible-light absorption. In practical environmental applications, the PPy@ZNF nanohybrid demonstrated superior photocatalytic activity compared to ZNF alone, degrading 98.5% of malachite green dye under W-lamp light within 80 minutes, with a rate constant of 0.031 min-1. Scavenger and cyclic experiments identified the active species involved in dye degradation and assessed the reusability of the nanohybrid. Extensive testing revealed the optimal conditions for photocatalytic efficiency; the considered variables included light intensity, catalyst dose, dye concentration, temperature, irradiation time, and pH. These findings suggest that the PPy-reinforced ZNF nanohybrid offers cost-effectiveness, magnetic recoverability, structural stability, and high efficacy as a visible light-driven catalyst, making it a promising candidate for diverse environmental remediation applications.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.