{"title":"利用综合二维气相色谱质谱法深入分析从废弃食用油中提取的生物航空燃料的多组分成分","authors":"Yang Xu, Xuan Guo, Meng Wang, Yunming Fang","doi":"10.1007/s11705-024-2494-1","DOIUrl":null,"url":null,"abstract":"<div><p>The characterization of bio-aviation fuel composition is paramount for assessing biomass conversion processes and its suitability to meet international standards. Compared with one-dimensional gas chromatography mass spectrometry (1DGC-MS), comprehensive two-dimensional gas chromatography with mass spectrometry (GC × GC-MS) emerges as a promising analytical approach for bio-aviation fuel, offering enhanced separation, resolution, selectivity, and sensitivity. This study addresses the qualitative and quantitative analysis methods for both bulk components and trace fatty acid methyl ester (FAME) in bio-aviation fuel obtained by hydrogenation at 400 °C with Ni-Mo/<i>γ</i>-Al<sub>2</sub>O<sub>3</sub>&Meso-SAPO-11 as catalyst using GC × GC-MS. In bulk composition analysis, C<sub>12</sub> concentration was highest at 25.597%. Based on GC × GC-MS analysis platform, the quality control method of FAME in bio-aviation fuel was established. At the split ratio of 10:1, limits of detections of six FAMEs were 0.011–0.027 mg·kg<sup>−1</sup>, and limits of quantifications were 0.036–0.090 mg·kg<sup>−1</sup>, and the GC × GC-MS research platform had the ability to detect FAME from 2 to 5 mg·kg<sup>−1</sup>. The results showed that this bioaviation fuel did not contain FAME.\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 12","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"In-depth multi-component analysis of bio-aviation fuel derived from waste cooking oil using comprehensive two-dimensional gas chromatography mass spectrometry\",\"authors\":\"Yang Xu, Xuan Guo, Meng Wang, Yunming Fang\",\"doi\":\"10.1007/s11705-024-2494-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The characterization of bio-aviation fuel composition is paramount for assessing biomass conversion processes and its suitability to meet international standards. Compared with one-dimensional gas chromatography mass spectrometry (1DGC-MS), comprehensive two-dimensional gas chromatography with mass spectrometry (GC × GC-MS) emerges as a promising analytical approach for bio-aviation fuel, offering enhanced separation, resolution, selectivity, and sensitivity. This study addresses the qualitative and quantitative analysis methods for both bulk components and trace fatty acid methyl ester (FAME) in bio-aviation fuel obtained by hydrogenation at 400 °C with Ni-Mo/<i>γ</i>-Al<sub>2</sub>O<sub>3</sub>&Meso-SAPO-11 as catalyst using GC × GC-MS. In bulk composition analysis, C<sub>12</sub> concentration was highest at 25.597%. Based on GC × GC-MS analysis platform, the quality control method of FAME in bio-aviation fuel was established. At the split ratio of 10:1, limits of detections of six FAMEs were 0.011–0.027 mg·kg<sup>−1</sup>, and limits of quantifications were 0.036–0.090 mg·kg<sup>−1</sup>, and the GC × GC-MS research platform had the ability to detect FAME from 2 to 5 mg·kg<sup>−1</sup>. The results showed that this bioaviation fuel did not contain FAME.\\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":571,\"journal\":{\"name\":\"Frontiers of Chemical Science and Engineering\",\"volume\":\"18 12\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Chemical Science and Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11705-024-2494-1\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-024-2494-1","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
In-depth multi-component analysis of bio-aviation fuel derived from waste cooking oil using comprehensive two-dimensional gas chromatography mass spectrometry
The characterization of bio-aviation fuel composition is paramount for assessing biomass conversion processes and its suitability to meet international standards. Compared with one-dimensional gas chromatography mass spectrometry (1DGC-MS), comprehensive two-dimensional gas chromatography with mass spectrometry (GC × GC-MS) emerges as a promising analytical approach for bio-aviation fuel, offering enhanced separation, resolution, selectivity, and sensitivity. This study addresses the qualitative and quantitative analysis methods for both bulk components and trace fatty acid methyl ester (FAME) in bio-aviation fuel obtained by hydrogenation at 400 °C with Ni-Mo/γ-Al2O3&Meso-SAPO-11 as catalyst using GC × GC-MS. In bulk composition analysis, C12 concentration was highest at 25.597%. Based on GC × GC-MS analysis platform, the quality control method of FAME in bio-aviation fuel was established. At the split ratio of 10:1, limits of detections of six FAMEs were 0.011–0.027 mg·kg−1, and limits of quantifications were 0.036–0.090 mg·kg−1, and the GC × GC-MS research platform had the ability to detect FAME from 2 to 5 mg·kg−1. The results showed that this bioaviation fuel did not contain FAME.
期刊介绍：
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
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