Ying Zhang , Chengshan Dai , Hongyu Fan , Junnan Chen , Li Gao , Bingsen Zhang
{"title":"PdCu/alpha-Fe2O3 催化剂的形态对 Suzukii-Miyaura 交叉偶联反应的支撑效应","authors":"Ying Zhang , Chengshan Dai , Hongyu Fan , Junnan Chen , Li Gao , Bingsen Zhang","doi":"10.1016/j.partic.2024.08.007","DOIUrl":null,"url":null,"abstract":"<div><p>The palladium-catalyzed Suzuki-Miyaura cross-coupling (SMC) reaction has received worldwide attention as a powerful and convenient synthetic tool for the formation of biaryl compounds. However, these reactions are highly dependent on the activity and stable of catalysts. Herein, the support morphology-dependent catalytic performance of SMC reactions was investigated. The truncated hexagonal bipyramid (α-Fe<sub>2</sub>O<sub>3</sub>-O) and rod-shaped morphologies of alpha-Fe<sub>2</sub>O<sub>3</sub> (α-Fe<sub>2</sub>O<sub>3</sub>-R) were used as support to prepare PdCu nanoparticles (NPs) catalysts by NaBH<sub>4</sub> reduction method. For PdCu/α-Fe<sub>2</sub>O<sub>3</sub>-R catalysts, the smaller size of PdCu NPs and more low coordination Pd sites leading to its superior catalytic performance for SMC reactions. Furthermore, it can be easily recycled through centrifugation and reused several times without obvious loss on its catalytic performance. Identical location transmission electron microscopy method was used to investigate the structural evolution of PdCu/α-Fe<sub>2</sub>O<sub>3</sub>-R catalysts. The results found that its structure almost unchanged during the catalytic reaction.</p></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"94 ","pages":"Pages 274-280"},"PeriodicalIF":4.1000,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Morphology-dependent support effect of PdCu/alpha-Fe2O3 catalysts on Suzuki-Miyaura cross-coupling reaction\",\"authors\":\"Ying Zhang , Chengshan Dai , Hongyu Fan , Junnan Chen , Li Gao , Bingsen Zhang\",\"doi\":\"10.1016/j.partic.2024.08.007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The palladium-catalyzed Suzuki-Miyaura cross-coupling (SMC) reaction has received worldwide attention as a powerful and convenient synthetic tool for the formation of biaryl compounds. However, these reactions are highly dependent on the activity and stable of catalysts. Herein, the support morphology-dependent catalytic performance of SMC reactions was investigated. The truncated hexagonal bipyramid (α-Fe<sub>2</sub>O<sub>3</sub>-O) and rod-shaped morphologies of alpha-Fe<sub>2</sub>O<sub>3</sub> (α-Fe<sub>2</sub>O<sub>3</sub>-R) were used as support to prepare PdCu nanoparticles (NPs) catalysts by NaBH<sub>4</sub> reduction method. For PdCu/α-Fe<sub>2</sub>O<sub>3</sub>-R catalysts, the smaller size of PdCu NPs and more low coordination Pd sites leading to its superior catalytic performance for SMC reactions. Furthermore, it can be easily recycled through centrifugation and reused several times without obvious loss on its catalytic performance. Identical location transmission electron microscopy method was used to investigate the structural evolution of PdCu/α-Fe<sub>2</sub>O<sub>3</sub>-R catalysts. The results found that its structure almost unchanged during the catalytic reaction.</p></div>\",\"PeriodicalId\":401,\"journal\":{\"name\":\"Particuology\",\"volume\":\"94 \",\"pages\":\"Pages 274-280\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-08-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Particuology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1674200124001627\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Particuology","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1674200124001627","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Morphology-dependent support effect of PdCu/alpha-Fe2O3 catalysts on Suzuki-Miyaura cross-coupling reaction
The palladium-catalyzed Suzuki-Miyaura cross-coupling (SMC) reaction has received worldwide attention as a powerful and convenient synthetic tool for the formation of biaryl compounds. However, these reactions are highly dependent on the activity and stable of catalysts. Herein, the support morphology-dependent catalytic performance of SMC reactions was investigated. The truncated hexagonal bipyramid (α-Fe2O3-O) and rod-shaped morphologies of alpha-Fe2O3 (α-Fe2O3-R) were used as support to prepare PdCu nanoparticles (NPs) catalysts by NaBH4 reduction method. For PdCu/α-Fe2O3-R catalysts, the smaller size of PdCu NPs and more low coordination Pd sites leading to its superior catalytic performance for SMC reactions. Furthermore, it can be easily recycled through centrifugation and reused several times without obvious loss on its catalytic performance. Identical location transmission electron microscopy method was used to investigate the structural evolution of PdCu/α-Fe2O3-R catalysts. The results found that its structure almost unchanged during the catalytic reaction.
期刊介绍：
The word ‘particuology’ was coined to parallel the discipline for the science and technology of particles.
Particuology is an interdisciplinary journal that publishes frontier research articles and critical reviews on the discovery, formulation and engineering of particulate materials, processes and systems. It especially welcomes contributions utilising advanced theoretical, modelling and measurement methods to enable the discovery and creation of new particulate materials, and the manufacturing of functional particulate-based products, such as sensors.
Papers are handled by Thematic Editors who oversee contributions from specific subject fields. These fields are classified into: Particle Synthesis and Modification; Particle Characterization and Measurement; Granular Systems and Bulk Solids Technology; Fluidization and Particle-Fluid Systems; Aerosols; and Applications of Particle Technology.
Key topics concerning the creation and processing of particulates include:
-Modelling and simulation of particle formation, collective behaviour of particles and systems for particle production over a broad spectrum of length scales
-Mining of experimental data for particle synthesis and surface properties to facilitate the creation of new materials and processes
-Particle design and preparation including controlled response and sensing functionalities in formation, delivery systems and biological systems, etc.
-Experimental and computational methods for visualization and analysis of particulate system.
These topics are broadly relevant to the production of materials, pharmaceuticals and food, and to the conversion of energy resources to fuels and protection of the environment.
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