Xuhui Pei , Yin Du , Hanming Wang , Mingchuan Hu , Yuehui Li , Wei Zhou , Haifeng Wang
{"title":"利用火花等离子烧结技术实现原位陶瓷相增强 NbMoWTa 难熔高熵合金复合材料的优异耐磨性","authors":"Xuhui Pei , Yin Du , Hanming Wang , Mingchuan Hu , Yuehui Li , Wei Zhou , Haifeng Wang","doi":"10.1016/j.wear.2024.205572","DOIUrl":null,"url":null,"abstract":"<div><p>The refractory high-entropy alloys (RHEAs) exhibit great potential as structural components for aerospace equipment. However, their lack of wear resistance and increased coefficient of friction at room temperature (RT) impose limitations on their practical applications. Therefore, further enhancements are required to improve their friction and wear properties under RT. In this context, the development of NbMoWTa(h-BN)<sub><em>x</em></sub> RHEA ceramic composites in this work offers a viable solution to address this issue. Experimental results demonstrate that the addition of <em>h</em>-BN leads to the in-situ generation of (Nb,Ta)N/(Nb,Ta)<sub>2</sub>N and (Nb,Ta)B<sub>2</sub> ceramic phases, significantly enhancing the hardness and wear resistance of the composites. The wear rate of NbMoWTa(<em>h</em>-BN)<sub>0.5</sub> reaching as low as 1.32 × 10<sup>−8</sup> mm<sup>3</sup>/Nm, which is four orders of magnitude lower than that of the RHEA. The NbMoWTa RHEA exhibits significant adhesive wear, which can be effectively mitigated in composites through the uniform dispersion of ceramic phase particles with lower mean free path. The abrasive particles primarily interact with the hard strengthening phase, effectively inhibiting plastic deformation in their vicinity. Consequently, the reduced mean free path between the ceramic phases limits the likelihood of metal matrix removal. Subsequently, aided by the presence of ceramic phases, the spontaneous formation of protective third bodies further inhibit surface material removal and ultimately ensures exceptional wear resistance.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"558 ","pages":"Article 205572"},"PeriodicalIF":5.3000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Attaining exceptional wear resistance in an in-situ ceramic phase reinforced NbMoWTa refractory high entropy alloy composite by Spark plasma sintering\",\"authors\":\"Xuhui Pei , Yin Du , Hanming Wang , Mingchuan Hu , Yuehui Li , Wei Zhou , Haifeng Wang\",\"doi\":\"10.1016/j.wear.2024.205572\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The refractory high-entropy alloys (RHEAs) exhibit great potential as structural components for aerospace equipment. However, their lack of wear resistance and increased coefficient of friction at room temperature (RT) impose limitations on their practical applications. Therefore, further enhancements are required to improve their friction and wear properties under RT. In this context, the development of NbMoWTa(h-BN)<sub><em>x</em></sub> RHEA ceramic composites in this work offers a viable solution to address this issue. Experimental results demonstrate that the addition of <em>h</em>-BN leads to the in-situ generation of (Nb,Ta)N/(Nb,Ta)<sub>2</sub>N and (Nb,Ta)B<sub>2</sub> ceramic phases, significantly enhancing the hardness and wear resistance of the composites. The wear rate of NbMoWTa(<em>h</em>-BN)<sub>0.5</sub> reaching as low as 1.32 × 10<sup>−8</sup> mm<sup>3</sup>/Nm, which is four orders of magnitude lower than that of the RHEA. The NbMoWTa RHEA exhibits significant adhesive wear, which can be effectively mitigated in composites through the uniform dispersion of ceramic phase particles with lower mean free path. The abrasive particles primarily interact with the hard strengthening phase, effectively inhibiting plastic deformation in their vicinity. Consequently, the reduced mean free path between the ceramic phases limits the likelihood of metal matrix removal. Subsequently, aided by the presence of ceramic phases, the spontaneous formation of protective third bodies further inhibit surface material removal and ultimately ensures exceptional wear resistance.</p></div>\",\"PeriodicalId\":23970,\"journal\":{\"name\":\"Wear\",\"volume\":\"558 \",\"pages\":\"Article 205572\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Wear\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0043164824003375\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, MECHANICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Wear","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0043164824003375","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
Attaining exceptional wear resistance in an in-situ ceramic phase reinforced NbMoWTa refractory high entropy alloy composite by Spark plasma sintering
The refractory high-entropy alloys (RHEAs) exhibit great potential as structural components for aerospace equipment. However, their lack of wear resistance and increased coefficient of friction at room temperature (RT) impose limitations on their practical applications. Therefore, further enhancements are required to improve their friction and wear properties under RT. In this context, the development of NbMoWTa(h-BN)x RHEA ceramic composites in this work offers a viable solution to address this issue. Experimental results demonstrate that the addition of h-BN leads to the in-situ generation of (Nb,Ta)N/(Nb,Ta)2N and (Nb,Ta)B2 ceramic phases, significantly enhancing the hardness and wear resistance of the composites. The wear rate of NbMoWTa(h-BN)0.5 reaching as low as 1.32 × 10−8 mm3/Nm, which is four orders of magnitude lower than that of the RHEA. The NbMoWTa RHEA exhibits significant adhesive wear, which can be effectively mitigated in composites through the uniform dispersion of ceramic phase particles with lower mean free path. The abrasive particles primarily interact with the hard strengthening phase, effectively inhibiting plastic deformation in their vicinity. Consequently, the reduced mean free path between the ceramic phases limits the likelihood of metal matrix removal. Subsequently, aided by the presence of ceramic phases, the spontaneous formation of protective third bodies further inhibit surface material removal and ultimately ensures exceptional wear resistance.
期刊介绍:
Wear journal is dedicated to the advancement of basic and applied knowledge concerning the nature of wear of materials. Broadly, topics of interest range from development of fundamental understanding of the mechanisms of wear to innovative solutions to practical engineering problems. Authors of experimental studies are expected to comment on the repeatability of the data, and whenever possible, conduct multiple measurements under similar testing conditions. Further, Wear embraces the highest standards of professional ethics, and the detection of matching content, either in written or graphical form, from other publications by the current authors or by others, may result in rejection.