固化体系对全沙漠砂工程水泥基复合材料机械性能和微观结构的影响

IF 4.4 2区 化学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Hengde Liu, Duotian Xia, Duo Zhang
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引用次数: 0

摘要

为了建立一种有利于快速提高和稳定改善全沙漠砂工程水泥基复合材料(DSECC)早期强度和拉伸延性的固化体系,并使其与生产效率相一致,本研究考察了不同固化体系(标准固化、自然固化、20℃水固化和 90℃水浴固化)对 DSECC 力学性能和微观结构的影响。研究结果表明,90℃水浴固化有利于提高 DSECC 的力学性能,其早期 7 天强度和拉伸变形能力(达 7.05%)可达到或超过标准固化 28 天的水平。在单轴拉伸试验中,在 20℃ 水中固化的样品裂纹宽度增加,裂纹数量减少,导致极限拉伸应变从 14 天时的 4.96 % 急剧下降到 28 天时的 1.57 %。自然固化导致 28 天时强度下降。微观结构分析表明,90℃水浴固化促进了高密度 C-S-H 凝胶的发展和沙漠砂的溶解,同时保持了纤维的完整性,增强了纤维-基质界面过渡区(ITZ)。90℃ 水浴固化条件下的孔隙特征参数更优越,显著细化了 DSECC 基质的孔隙尺寸。20℃ 水浴固化可以弥补沙漠砂造成的缺陷,提高基质-集料 ITZ 的致密性。自然固化产生的基质水化程度最低,孔隙率高达 41.90%,小于 50 nm 的孔隙仅占 8.97%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of curing regimes on mechanical properties and microstructure of engineered cementitious composites with full desert sand

To establish a curing regime that facilitates the rapid enhancement and stable progression of early-age strength and tensile ductility in engineered cementitious composites with full desert sand (DSECC), aligning with production efficiency, this study examines the effects of different curing regimes (standard curing, natural curing, 20℃ water curing, and 90℃ water bath curing) on DSECC 's the mechanical properties and microstructure. The findings indicate that 90℃ water bath curing is beneficial to enhance the mechanical properties of DSECC, and its early 7 days strength and tensile deformation capacity (up to 7.05 %) can reach or exceed the standard curing 28 days level. In the uniaxial tensile test, samples cured in 20℃ water exhibit increased crack widths and reduced crack numbers, resulting in a sharp decline in the ultimate tensile strain from 4.96 % at 14 days to 1.57 % at 28 days. Natural curing leads to regression in strength at 28 days. The microstructure analysis revealed that 90℃ water bath curing fostered the development of high-density C-S-H gel and the dissolution of desert sand, while preserving the integrity of the fibers, enhancing the fiber-matrix interface transition zone (ITZ). The pore characteristic parameters under 90℃ water bath curing are superior, which has a notable refinement of the DSECC matrix's pore size. 20℃ Water curing can make up for the defects caused by desert sand and improve the compactness of matrix-aggregate ITZ. Natural curing yields the lowest degree of matrix hydration, with porosity reaching as high as 41.90 %, and pores smaller than 50 nm accounting for only 8.97 %.

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来源期刊
CiteScore
7.20
自引率
6.00%
发文量
810
期刊介绍: ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.
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