Chemometric heavy metal contamination in tropical Indian estuaries: Implications for source identification

The impact of urban and industrial effluents in the tropical Indian estuaries (Ariankuppam backwater and Chunnambar River), east coast of India have been investigated in the present study by determining the degree of heavy metals contamination of the estuarine sediments. A total of 30 surface sediment samples were collected from both estuaries and were analyzed for trace metals, grain size and organic matter. The granulometric analysis reveals that both the estuaries are predominated by silty sand to sandy silt. The significant amount of organic matter (OM) in the Ariankuppam estuary sediment is due to natural (mangroves) and anthropogenic (pollution) organic input. Pearson correlation analysis reveals that there was a strong negative correlation of sand fraction with other sediment variables (silt, clay, and organic matter) and heavy metals, whereas a positive correlation was observed between silt+clay, organic matter, and heavy metals. The significant positive correlation of Fe with Ni, Cu, Pb and Zn presents Fe-Mn oxyhydroxides are the main controlling factor of heavy metals in both estuarine sediments. Cluster analysis and PCA helped to discriminate the station groups along both estuaries according to their sediment components and heavy metals. This study also revealed that sediment grain size is a key factor influencing organic matter and heavy metal accumulation in surface sediments. The calculated pollution indices such as Contamination factor (CF), Geoaccumulation Index (Igeo) and Pollution Load Index (PLI) values indicate that both estuaries are moderate to highly contaminated by Co and low to moderately contaminated by Pb and Zn. Based on the factor analysis, it is presumed that river runoff and industrial and untreated domestic wastes from lands are responsible for increased heavy metal concentration in both estuaries. Increased levels of metal contamination along the Union Territory of Puducherry coastline may increase the risk of human exposure to metals through the consumption of seafood, making the need for tougher regulations on the discharge of metals into the environment even more important.