通过钯催化串联铃木偶联/赫克环化反应合成双环芳香烯和相关多环系统

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2024-09-07 DOI:10.1016/j.tetlet.2024.155297

{"title":"通过钯催化串联铃木偶联/赫克环化反应合成双环芳香烯和相关多环系统","authors":"","doi":"10.1016/j.tetlet.2024.155297","DOIUrl":null,"url":null,"abstract":"<div><p>A variety of bistricyclic aromatic enes (BAEs) and its derivatives have been prepared via the palladium-catalyzed Suzuki coupling/Heck cyclization tandem reaction in one pot. In the new proposal the expected products were obtained in exciting yields at nearly equimolar ratios of the substrates. It is very useful method for the synthesis of the fluorenylidene-based BAEs. Even the corresponding ladder-type conjugated polymer was also prepared by the tandem reaction.</p></div>","PeriodicalId":438,"journal":{"name":"Tetrahedron Letters","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of bistricyclic aromatic enes and related polycyclic systems via Pd-catalyzed tandem Suzuki coupling/Heck cyclization reaction\",\"authors\":\"\",\"doi\":\"10.1016/j.tetlet.2024.155297\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A variety of bistricyclic aromatic enes (BAEs) and its derivatives have been prepared via the palladium-catalyzed Suzuki coupling/Heck cyclization tandem reaction in one pot. In the new proposal the expected products were obtained in exciting yields at nearly equimolar ratios of the substrates. It is very useful method for the synthesis of the fluorenylidene-based BAEs. Even the corresponding ladder-type conjugated polymer was also prepared by the tandem reaction.</p></div>\",\"PeriodicalId\":438,\"journal\":{\"name\":\"Tetrahedron Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-09-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0040403924003927\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040403924003927","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

摘要

通过钯催化的铃木偶联/赫克环化串联反应，在一锅内制备出了多种双环芳香烯（BAEs）及其衍生物。在新方案中，以几乎等摩尔比的底物获得了令人兴奋的预期产物。这是一种非常有用的合成亚芴基 BAE 的方法。通过串联反应，还制备出了相应的梯形共轭聚合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of bistricyclic aromatic enes and related polycyclic systems via Pd-catalyzed tandem Suzuki coupling/Heck cyclization reaction

查看原文本刊更多论文

Synthesis of bistricyclic aromatic enes and related polycyclic systems via Pd-catalyzed tandem Suzuki coupling/Heck cyclization reaction

A variety of bistricyclic aromatic enes (BAEs) and its derivatives have been prepared via the palladium-catalyzed Suzuki coupling/Heck cyclization tandem reaction in one pot. In the new proposal the expected products were obtained in exciting yields at nearly equimolar ratios of the substrates. It is very useful method for the synthesis of the fluorenylidene-based BAEs. Even the corresponding ladder-type conjugated polymer was also prepared by the tandem reaction.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.