Hongmin Liu, Xinran Gao, Yitao Lou, Hua Kun Liu, Shi Xue Dou, Zhongchao Bai, Nana Wang
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Coupled Photochemical Storage Materials in Solar Rechargeable Batteries: Progress, Challenges, and Prospects
Solar rechargeable batteries (SRBs), as an emerging technology for harnessing solar energy, integrate the advantages of photochemical devices and redox batteries to synergistically couple dual-functional materials capable of both light harvesting and redox activity. This enables direct solar-to-electrochemical energy storage within a single system. However, the mismatch in energy levels between coupled photochemical storage materials (PSMs) and the occurrence of side reactions with liquid electrolytes during charge-discharge cycles lead to a decrease in solar energy conversion efficiency. This impedes the advancement of SRBs. This review comprehensively discusses of the latest advancements in PSMs, which are crucial for designing advanced SRBs. It delves into an extensive discussion of the design criteria for dual-functional photochemical storage cathodes (PSCs) and elucidates the operational mechanism of SRBs. Additionally, it further discusses the performance, efficiency, and long-term cycle stability of SRBs in relation to photoelectronic and photothermal mechanisms. Finally, an outlook on primary challenges and prospects that SRBs will encounter is provided to offer novel insights for their technological advancement.
期刊介绍:
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.