显示固态发射的高价锡(iv)融合偶氮/偶氮亚甲基化合物的简便机械化学合成†

Masayuki Gon, Taichi Kato, Kazuya Tanimura, Chiaki Hotta and Kazuo Tanaka
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引用次数: 0

摘要

机械化学合成涉及无溶剂化学反应,作为绿色化学备受关注。在此,我们展示了通过在玛瑙研钵中手工研磨,以偶氮/偶氮金属三叉配体和有机锡(IV)氧化物为原料,无溶剂和催化剂机械化学合成高价锡(IV)化合物的方法。傅立叶变换红外光谱显示,根据反应条件的不同,41%-82% 的配体可转化为高价锡化合物。生成的产物在黄色至深红色区域呈现固态发射,无需提纯。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Facile mechanochemical synthesis of hypervalent tin(iv)-fused azo/azomethine compounds showing solid-state emission†

Facile mechanochemical synthesis of hypervalent tin(iv)-fused azo/azomethine compounds showing solid-state emission†

Mechanochemical synthesis involves carrying out chemical reactions without solvents and has attracted much attention as green chemistry. Herein, we demonstrate solvent- and catalyst-free mechanochemical synthesis of hypervalent tin(IV) compounds with azo/azomethine tridentate ligands and organotin(IV) oxide by manual grinding in an agate mortar. FT-IR spectra indicate that 41–82% of the ligands can be converted to hypervalent tin compounds depending on the reaction conditions. The resulting products exhibit solid-state emission in the yellow to deep-red region without purification.

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