Xiangyue Liu , Nan Meng , Shengli Zhang , Shiying Guo , Yanlin Kang , Guangzhao Wang , Bing Li , Zhaoyang Lou
{"title":"观察基于 Nb2CTx 的锥形多芯纤维在湿度传感中的应用:实验和 DFT 模拟研究","authors":"Xiangyue Liu , Nan Meng , Shengli Zhang , Shiying Guo , Yanlin Kang , Guangzhao Wang , Bing Li , Zhaoyang Lou","doi":"10.1016/j.surfin.2024.105042","DOIUrl":null,"url":null,"abstract":"<div><p>Recent advancements in the area of human healthcare monitoring and medical diagnosis have sparked a revived interest in humidity sensors. Nb<sub>2</sub>CT<sub>x</sub>, characterized by its multilayered structure, large specific surface area, and plentiful hydrophilic groups, actively absorbs a sufficient quantity of water molecules. In this work, the sensing capability and mechanism of water molecules are investigated under different proportions of functional group distribution on the surface of Nb<sub>2</sub>CT<sub>x</sub> MXene employing plane-wave based density functional theory calculations, and the provided models can offer guiding principles for the experimental preparation of the highly sensitive humidity sensor based on Nb<sub>2</sub>CT<sub>x</sub>. To verify the effectiveness of the model, Nb<sub>2</sub>CT<sub>x</sub> material is coated on a Tapered Three-Core Fiber (TTCF), and the high evanescent field characteristics of the sensor are utilized to further improve its performance. As the relative humidity (RH) increased from 35 % to 75 %, the transmitted spectra exhibited a redshift with a sensitivity of 22pm/% RH. Within the relative humidity range of 75 % to 95 %, the Nb<sub>2</sub>CT<sub>x</sub> coating heightened water molecule absorption, resulting in a more pronounced redshift in the transmitted spectra. This phase manifests a maximum humidity sensitivity of 299pm/% RH. Noteworthy advantages of this sensor include its uncomplicated structure, cost-effectiveness, and robust stability, rendering it highly suitable a wide variety of potential applications in fields such as biology, chemical and health processing.</p></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"53 ","pages":"Article 105042"},"PeriodicalIF":5.7000,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Observation of tapered multicore fibers based on Nb2CTx for humidity sensing: Experiment and DFT simulation investigations\",\"authors\":\"Xiangyue Liu , Nan Meng , Shengli Zhang , Shiying Guo , Yanlin Kang , Guangzhao Wang , Bing Li , Zhaoyang Lou\",\"doi\":\"10.1016/j.surfin.2024.105042\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Recent advancements in the area of human healthcare monitoring and medical diagnosis have sparked a revived interest in humidity sensors. Nb<sub>2</sub>CT<sub>x</sub>, characterized by its multilayered structure, large specific surface area, and plentiful hydrophilic groups, actively absorbs a sufficient quantity of water molecules. In this work, the sensing capability and mechanism of water molecules are investigated under different proportions of functional group distribution on the surface of Nb<sub>2</sub>CT<sub>x</sub> MXene employing plane-wave based density functional theory calculations, and the provided models can offer guiding principles for the experimental preparation of the highly sensitive humidity sensor based on Nb<sub>2</sub>CT<sub>x</sub>. To verify the effectiveness of the model, Nb<sub>2</sub>CT<sub>x</sub> material is coated on a Tapered Three-Core Fiber (TTCF), and the high evanescent field characteristics of the sensor are utilized to further improve its performance. As the relative humidity (RH) increased from 35 % to 75 %, the transmitted spectra exhibited a redshift with a sensitivity of 22pm/% RH. Within the relative humidity range of 75 % to 95 %, the Nb<sub>2</sub>CT<sub>x</sub> coating heightened water molecule absorption, resulting in a more pronounced redshift in the transmitted spectra. This phase manifests a maximum humidity sensitivity of 299pm/% RH. Noteworthy advantages of this sensor include its uncomplicated structure, cost-effectiveness, and robust stability, rendering it highly suitable a wide variety of potential applications in fields such as biology, chemical and health processing.</p></div>\",\"PeriodicalId\":22081,\"journal\":{\"name\":\"Surfaces and Interfaces\",\"volume\":\"53 \",\"pages\":\"Article 105042\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2024-09-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surfaces and Interfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2468023024011982\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surfaces and Interfaces","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468023024011982","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Observation of tapered multicore fibers based on Nb2CTx for humidity sensing: Experiment and DFT simulation investigations
Recent advancements in the area of human healthcare monitoring and medical diagnosis have sparked a revived interest in humidity sensors. Nb2CTx, characterized by its multilayered structure, large specific surface area, and plentiful hydrophilic groups, actively absorbs a sufficient quantity of water molecules. In this work, the sensing capability and mechanism of water molecules are investigated under different proportions of functional group distribution on the surface of Nb2CTx MXene employing plane-wave based density functional theory calculations, and the provided models can offer guiding principles for the experimental preparation of the highly sensitive humidity sensor based on Nb2CTx. To verify the effectiveness of the model, Nb2CTx material is coated on a Tapered Three-Core Fiber (TTCF), and the high evanescent field characteristics of the sensor are utilized to further improve its performance. As the relative humidity (RH) increased from 35 % to 75 %, the transmitted spectra exhibited a redshift with a sensitivity of 22pm/% RH. Within the relative humidity range of 75 % to 95 %, the Nb2CTx coating heightened water molecule absorption, resulting in a more pronounced redshift in the transmitted spectra. This phase manifests a maximum humidity sensitivity of 299pm/% RH. Noteworthy advantages of this sensor include its uncomplicated structure, cost-effectiveness, and robust stability, rendering it highly suitable a wide variety of potential applications in fields such as biology, chemical and health processing.
期刊介绍:
The aim of the journal is to provide a respectful outlet for ''sound science'' papers in all research areas on surfaces and interfaces. We define sound science papers as papers that describe new and well-executed research, but that do not necessarily provide brand new insights or are merely a description of research results.
Surfaces and Interfaces publishes research papers in all fields of surface science which may not always find the right home on first submission to our Elsevier sister journals (Applied Surface, Surface and Coatings Technology, Thin Solid Films)