具有芳香环共轭嵌合功能的壳寡糖衍生物分散沥青质以降低重油粘度

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS
Jie Yu, Hongping Quan*, Jia Xiao, Jingran Wang, Lilong Zhang, Xueshuo Chang, Shuaibin Peng, Jinyu Wang* and Zhiyu Huang*, 
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引用次数: 0

摘要

在分散沥青质堆积结构和抑制沥青质重新聚集的基础上,本研究利用壳聚糖低聚糖(COS)制备了功能性壳聚糖低聚糖(COS)衍生物。在芳香环共轭插层的驱动下,COS 衍生物可在沥青烯叠层结构的层间移动。通过 X 射线衍射和拉曼光谱分析了 COS 衍生物对沥青烯聚集体面对面堆叠和芳香片内径的影响。场发射扫描电子显微镜和高分辨率透射电子显微镜可以观察到这种相互作用模式下沥青质的微观结构。COS 衍生物对沥青质堆叠结构和聚集行为的影响可以提高重油的流动性,从而改变重油的粘度-温度曲线。这表明 COS 衍生物在重油开采和输送方面具有巨大的研究价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Chitooligosaccharide Derivatives with Aromatic Ring Conjugated Intercalation Function Disperse Asphaltene to Reduce the Viscosity of Heavy Oil

Chitooligosaccharide Derivatives with Aromatic Ring Conjugated Intercalation Function Disperse Asphaltene to Reduce the Viscosity of Heavy Oil

Based on dispersing the stacking structure of asphaltenes and inhibiting the reaggregation of asphaltenes, functional chitosan oligosaccharide (COS) derivatives were prepared using COS in this study. Driven by the conjugated intercalation of aromatic rings, COS derivatives could move among the lamellae of asphaltene stacked structures. The effect of COS derivatives on asphaltene aggregates for face-to-face stacking and the inner diameter of the aromatic sheet was characterized by X-ray diffraction and Raman. The microstructure of asphaltene in this mode of interaction could be observed by field emission scanning electron microscopy and high-resolution transmission electron microscopy. The effect of COS derivatives on the stacking structure and aggregation behavior of asphaltenes could enhance the fluidity of heavy oil, resulting in a change in the viscosity-temperature curve of heavy oil. This demonstrates the enormous research value of COS derivatives in the extraction and transportation of heavy oil.

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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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